| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-106 |
Sentence |
denotes |
Comparison of the 13C-N.M.R. spectra of gangliosides GM1 with those of GM1-oligosaccharide and asialo-GM1. |
| T1 |
0-106 |
Sentence |
denotes |
Comparison of the 13C-N.M.R. spectra of gangliosides GM1 with those of GM1-oligosaccharide and asialo-GM1. |
| TextSentencer_T2 |
107-306 |
Sentence |
denotes |
The 13C-n.m.r. spectra of asialo-GM1 and GM1-oligosaccharide are completely assigned and compared to those previously found for intact GM1 and for the series GM4, GM3, GM2, GM1, GD1a, GD1b, and GT1b. |
| T2 |
107-306 |
Sentence |
denotes |
The 13C-n.m.r. spectra of asialo-GM1 and GM1-oligosaccharide are completely assigned and compared to those previously found for intact GM1 and for the series GM4, GM3, GM2, GM1, GD1a, GD1b, and GT1b. |
| TextSentencer_T3 |
307-522 |
Sentence |
denotes |
Removal of the ceramide residue from GM1 liberated a free, reducing aldehyde group, which was reflected in a doubling of the 13C-n.m.r. signals assignable to the D-glucose residue because of alpha, beta equilibrium. |
| T3 |
307-522 |
Sentence |
denotes |
Removal of the ceramide residue from GM1 liberated a free, reducing aldehyde group, which was reflected in a doubling of the 13C-n.m.r. signals assignable to the D-glucose residue because of alpha, beta equilibrium. |
| TextSentencer_T4 |
523-767 |
Sentence |
denotes |
The spectrum of asialo-GM1 lacks the resonances from the sialic acid residue, as expected; in addition, several resonances from the neutral gangliotetraglycosyl residue shifted to different field positions after removal of sialic acid from GM1. |
| T4 |
523-767 |
Sentence |
denotes |
The spectrum of asialo-GM1 lacks the resonances from the sialic acid residue, as expected; in addition, several resonances from the neutral gangliotetraglycosyl residue shifted to different field positions after removal of sialic acid from GM1. |
| TextSentencer_T5 |
768-961 |
Sentence |
denotes |
These resonances include that of C-4 of the inner beta-D-galactosyl residue, and C-1 of the 2-acetamido-2-deoxy-D-galactosyl residue that is near the site of attachment of the sialosyl residue. |
| T5 |
768-961 |
Sentence |
denotes |
These resonances include that of C-4 of the inner beta-D-galactosyl residue, and C-1 of the 2-acetamido-2-deoxy-D-galactosyl residue that is near the site of attachment of the sialosyl residue. |
| TextSentencer_T6 |
962-1133 |
Sentence |
denotes |
The differences between the chemical shifts of the carbon resonances of oligomeric and monomeric saccharides, termed linkage shifts, provide a quantitative assignment aid. |
| T6 |
962-1133 |
Sentence |
denotes |
The differences between the chemical shifts of the carbon resonances of oligomeric and monomeric saccharides, termed linkage shifts, provide a quantitative assignment aid. |
| TextSentencer_T7 |
1134-1264 |
Sentence |
denotes |
They are approximately 1/3 of those for residues linked to sialic acid than those for residues linked to the neutral hexose chain. |
| T7 |
1134-1264 |
Sentence |
denotes |
They are approximately 1/3 of those for residues linked to sialic acid than those for residues linked to the neutral hexose chain. |
| TextSentencer_T8 |
1265-1542 |
Sentence |
denotes |
Correlations among linkage shifts for pairs of glycosidically-linked carbon atoms for asialo-GM1 and GM1-oligosaccharide were compared with those for the series of gangliosides GM4 to GT1b, and differences are noted for resonances for carbon atoms near the sialic acid residue. |
| T8 |
1265-1542 |
Sentence |
denotes |
Correlations among linkage shifts for pairs of glycosidically-linked carbon atoms for asialo-GM1 and GM1-oligosaccharide were compared with those for the series of gangliosides GM4 to GT1b, and differences are noted for resonances for carbon atoms near the sialic acid residue. |
| TextSentencer_T9 |
1543-1670 |
Sentence |
denotes |
The spectrum of ganglioside GM1b, a positional isomer of GM1 whose 13C-n.m.r. spectrum has not yet been observed, is predicted. |
| T9 |
1543-1670 |
Sentence |
denotes |
The spectrum of ganglioside GM1b, a positional isomer of GM1 whose 13C-n.m.r. spectrum has not yet been observed, is predicted. |