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PubMed:6437676 JSONTXT 39 Projects

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Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-161 Sentence denotes Conformational and dynamic differences between N. meningitidis serogroup B and C polysaccharides, using n.m.r. spectroscopy and molecular mechanics calculations.
T1 0-161 Sentence denotes Conformational and dynamic differences between N. meningitidis serogroup B and C polysaccharides, using n.m.r. spectroscopy and molecular mechanics calculations.
TextSentencer_T2 162-400 Sentence denotes 1H-N.m.r. spectroscopy has been used to determine the conformation in aqueous solution of the sialic acid residues of the N. meningitidis serogroup B and non-O-acetylated (O-Ac-)-C polysaccharides, and of N-acetylneuraminic acid (NeuNAc).
T2 162-400 Sentence denotes 1H-N.m.r. spectroscopy has been used to determine the conformation in aqueous solution of the sialic acid residues of the N. meningitidis serogroup B and non-O-acetylated (O-Ac-)-C polysaccharides, and of N-acetylneuraminic acid (NeuNAc).
TextSentencer_T3 401-453 Sentence denotes In all cases, the sugar adopts the 2C5 conformation.
T3 401-453 Sentence denotes In all cases, the sugar adopts the 2C5 conformation.
TextSentencer_T4 454-557 Sentence denotes The side-chain of NeuNAc adopts a conformation such that H-7 and H-8 are approximately anti-periplanar.
T4 454-557 Sentence denotes The side-chain of NeuNAc adopts a conformation such that H-7 and H-8 are approximately anti-periplanar.
TextSentencer_T5 558-678 Sentence denotes This conformation is also found in the (O-Ac-)-C polysaccharide, whereas H-7 and H-8 are gauche in the B polysaccharide.
T5 558-678 Sentence denotes This conformation is also found in the (O-Ac-)-C polysaccharide, whereas H-7 and H-8 are gauche in the B polysaccharide.
TextSentencer_T6 679-893 Sentence denotes Molecular mechanics calculations have been used to probe the conformational preferences of the variously linked sialic acid residues, and the results are in general agreement with those based on the 1H-n.m.r. data.
T6 679-893 Sentence denotes Molecular mechanics calculations have been used to probe the conformational preferences of the variously linked sialic acid residues, and the results are in general agreement with those based on the 1H-n.m.r. data.
TextSentencer_T7 894-1035 Sentence denotes The 13C-n.m.r. spin-lattice relaxation-times have been interpreted in terms of the molecular dynamics of the B and (O-Ac-)-C polysaccharides.
T7 894-1035 Sentence denotes The 13C-n.m.r. spin-lattice relaxation-times have been interpreted in terms of the molecular dynamics of the B and (O-Ac-)-C polysaccharides.
TextSentencer_T8 1036-1151 Sentence denotes Molecular correlation times have been calculated and details of internal rotational or segmental motion elucidated.
T8 1036-1151 Sentence denotes Molecular correlation times have been calculated and details of internal rotational or segmental motion elucidated.
TextSentencer_T9 1152-1442 Sentence denotes The C polysaccharide is characterised by internal or segmental motion in the C-7 to C-9 side-chain of the sialic acid repeating-unit, whereas the B polysaccharide has little or no such movement and tumbles in solution as a rigid species with internal rotation of only the pendant C-9 group.
T9 1152-1442 Sentence denotes The C polysaccharide is characterised by internal or segmental motion in the C-7 to C-9 side-chain of the sialic acid repeating-unit, whereas the B polysaccharide has little or no such movement and tumbles in solution as a rigid species with internal rotation of only the pendant C-9 group.
TextSentencer_T10 1443-1574 Sentence denotes The conformational differences suggest a substantially different three-dimensional structure in solution for these polysaccharides.
T10 1443-1574 Sentence denotes The conformational differences suggest a substantially different three-dimensional structure in solution for these polysaccharides.