| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-88 |
Sentence |
denotes |
Stereoselective synthesis of 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides). |
| T1 |
0-88 |
Sentence |
denotes |
Stereoselective synthesis of 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides). |
| TextSentencer_T2 |
89-235 |
Sentence |
denotes |
The synthesis is described of highly acid-sensitive, 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides) as potential anti-cancer prodrugs. |
| T2 |
89-235 |
Sentence |
denotes |
The synthesis is described of highly acid-sensitive, 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides) as potential anti-cancer prodrugs. |
| TextSentencer_T3 |
236-641 |
Sentence |
denotes |
Reaction of 2,3,4,6-tetra-O-acetyl-1-O-trimethylsilyl-beta-D-glucopyranose (4) severally with various aliphatic and alicyclic ketones and methyl trimethylsilyl ether, in the presence of catalytic amounts of trimethylsilyl trifluoromethanesulfonate, afforded the corresponding acetylated acetal-beta-glucosides, e.g., acetone gave 1-methoxy-1-methylethyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside (7a). |
| T3 |
236-641 |
Sentence |
denotes |
Reaction of 2,3,4,6-tetra-O-acetyl-1-O-trimethylsilyl-beta-D-glucopyranose (4) severally with various aliphatic and alicyclic ketones and methyl trimethylsilyl ether, in the presence of catalytic amounts of trimethylsilyl trifluoromethanesulfonate, afforded the corresponding acetylated acetal-beta-glucosides, e.g., acetone gave 1-methoxy-1-methylethyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside (7a). |
| TextSentencer_T4 |
642-719 |
Sentence |
denotes |
Likewise the alpha-anomer (8a) of 7a was obtained from the alpha-anomer of 4. |
| T4 |
642-719 |
Sentence |
denotes |
Likewise the alpha-anomer (8a) of 7a was obtained from the alpha-anomer of 4. |
| TextSentencer_T5 |
720-805 |
Sentence |
denotes |
Deacetylation of the tetra-acetates then gave the acetal-alpha- and -beta-glucosides. |
| T5 |
720-805 |
Sentence |
denotes |
Deacetylation of the tetra-acetates then gave the acetal-alpha- and -beta-glucosides. |
