| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-117 |
Sentence |
denotes |
Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei. |
| T1 |
0-117 |
Sentence |
denotes |
Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei. |
| TextSentencer_T2 |
118-610 |
Sentence |
denotes |
The three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). |
| T2 |
118-610 |
Sentence |
denotes |
The three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). |
| TextSentencer_T3 |
611-730 |
Sentence |
denotes |
Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. |
| T3 |
611-730 |
Sentence |
denotes |
Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. |
| TextSentencer_T4 |
731-928 |
Sentence |
denotes |
Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. |
| T4 |
731-928 |
Sentence |
denotes |
Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. |
| TextSentencer_T5 |
929-1056 |
Sentence |
denotes |
Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. |
| T5 |
929-1056 |
Sentence |
denotes |
Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. |
| TextSentencer_T6 |
1057-1131 |
Sentence |
denotes |
Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. |
| T6 |
1057-1131 |
Sentence |
denotes |
Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. |
| TextSentencer_T7 |
1132-1281 |
Sentence |
denotes |
Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. |
| T7 |
1132-1281 |
Sentence |
denotes |
Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. |
| TextSentencer_T8 |
1282-1412 |
Sentence |
denotes |
Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei. |
| T8 |
1282-1412 |
Sentence |
denotes |
Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei. |