| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-83 |
Sentence |
denotes |
Synthesis of C-glycosyl compounds of N-acetylneuraminic acid from D-gluconolactone. |
| T1 |
0-83 |
Sentence |
denotes |
Synthesis of C-glycosyl compounds of N-acetylneuraminic acid from D-gluconolactone. |
| TextSentencer_T2 |
84-283 |
Sentence |
denotes |
A general strategy towards the synthesis of C-glycosyl compounds of N-acetylneuraminic acid (Neu5Ac) has been developed and successfully applied to the synthesis of C-methyl and C-phenyl derivatives. |
| T2 |
84-283 |
Sentence |
denotes |
A general strategy towards the synthesis of C-glycosyl compounds of N-acetylneuraminic acid (Neu5Ac) has been developed and successfully applied to the synthesis of C-methyl and C-phenyl derivatives. |
| TextSentencer_T3 |
284-662 |
Sentence |
denotes |
The key strategic elements are (i) chain extension of a D-gluconolactone derivative as C(6)-precursor with an allyl Grignard reagent as C(3)-precursor having in 2 position the C-linked aglycon moiety, (ii) stereoselective C-4/C-5 erythro-diol formation, (iii) 6-exo-trig selective heterocyclization, and (iv) installment of the 5-acetylamino and C-1 carboxylate functionalities. |
| T3 |
284-662 |
Sentence |
denotes |
The key strategic elements are (i) chain extension of a D-gluconolactone derivative as C(6)-precursor with an allyl Grignard reagent as C(3)-precursor having in 2 position the C-linked aglycon moiety, (ii) stereoselective C-4/C-5 erythro-diol formation, (iii) 6-exo-trig selective heterocyclization, and (iv) installment of the 5-acetylamino and C-1 carboxylate functionalities. |
| TextSentencer_T4 |
663-798 |
Sentence |
denotes |
The efficiency and potential versatility of this approach was exemplified in the synthesis of C-methyl derivative 1 as target molecule. |
| T4 |
663-798 |
Sentence |
denotes |
The efficiency and potential versatility of this approach was exemplified in the synthesis of C-methyl derivative 1 as target molecule. |
