PubMed:34954492 JSONTXT

{"target":"https://pubannotation.org/docs/sourcedb/PubMed/sourceid/34954492","sourcedb":"PubMed","sourceid":"34954492","source_url":"https://www.ncbi.nlm.nih.gov/pubmed/34954492","text":"Stereoselective total synthesis of (-)-hygrophorone A12 and 4-epi-2,3-dihydrohygrophorone H12.\nStereoselective total synthesis of anti-fungal cyclopentenone (-)-hygrophorone A12 and cyclopentanone 4-epi-2,3-dihydrohygrophorone H12 were achieved in high overall yields from d-ribose. An aqueous KOH mediated diastereoselective formation of β-hydroxy ketone with three contiguous chiral centres served as a key step in this synthesis.","tracks":[]}