PubMed:2171765 JSON TXT

Benzeneselenenyl triflate as an activator of thioglycosides for glycosylation reactions. A new method for the activation of thioglycosides was developed by use of benzeneselenenyl triflate (PhSeOTf), which, upon reaction with either a primary or secondary sugar HO-group, afforded O-glycosides under extremely mild reaction conditions. The reaction was applicable to various l-thiohexosides 2-6 as well as to a 2-thioglycoside 20 derived from N-acetylneuraminic acid (NeuAc).

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PubMed:2171765 JSONTXT

projects that include this document

PubMed:2171765 JSON TXT