| Id |
Subject |
Object |
Predicate |
Lexical cue |
| T1 |
0-129 |
Sentence |
denotes |
Synthesis of postulated molecular probes: stereoselective free-radical-mediated C-glycosylation in tandem with hydrogen transfer. |
| T2 |
130-310 |
Sentence |
denotes |
Reported herein is a strategy employing an addition reaction in tandem with a hydrogen-transfer reaction for the elaboration of C-glycoside-based sialyl Lewis X (sLe(X)) analogues. |
| T3 |
311-413 |
Sentence |
denotes |
Significant stereocontrol was noted when alkyl radicals were reacted with a series of alkoxytaconates. |
| T4 |
414-482 |
Sentence |
denotes |
Transition states were proposed to explain the obtained selectivity. |
| T5 |
483-651 |
Sentence |
denotes |
Further reaction between an anomeric-centered fucosyl-derived radical and a galactosylated hydroxytaconate provided easy access to C,O-diglycosides as mimics of sLe(X). |
| T6 |
652-793 |
Sentence |
denotes |
In this case, two 1,3-distant stereocenters were created with high diastereoselectivity using free radical intermediates in a tandem process. |
