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PubMed:9579799 JSONTXT

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GlyCosmos6-Glycan-Motif-Image

Id Subject Object Predicate Lexical cue image
T1 203-212 Glycan_Motif denotes galabiose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G62763GO
T2 320-326 Glycan_Motif denotes Neu5Ac https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G81533KY

sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-149 Sentence denotes Convergent synthesis of neoglycopeptides by coupling of 2-bromoethyl glycosides to cysteine and homocysteine residues in T cell stimulating peptides.
TextSentencer_T2 150-391 Sentence denotes The 2-bromoethyl beta-glycosides of the disaccharide galabiose [Gal(alpha1-4)Gal] and the trisaccharides globotriose [Gal(alpha1-4)Gal(beta1-4)Glc] and 3'-sialyllactose [Neu5Ac(alpha2-3)Gal(beta1-4)Glc] have been prepared by improved routes.
TextSentencer_T3 392-570 Sentence denotes The 2-bromoethyl glycosides were then used in cesium carbonate promoted alkylations of the sulfhydryl groups of cysteine and homocysteine residues in T cell stimulating peptides.
TextSentencer_T4 571-712 Sentence denotes This convergent and general approach was used to prepare 16 neoglycopeptides which were obtained in 52-95% yields after purification by HPLC.
TextSentencer_T5 713-850 Sentence denotes 1H NMR spectroscopy revealed that beta-elimination and epimerization of neoglycopeptide stereocentres did not occur during the synthesis.
T1 0-149 Sentence denotes Convergent synthesis of neoglycopeptides by coupling of 2-bromoethyl glycosides to cysteine and homocysteine residues in T cell stimulating peptides.
T2 150-391 Sentence denotes The 2-bromoethyl beta-glycosides of the disaccharide galabiose [Gal(alpha1-4)Gal] and the trisaccharides globotriose [Gal(alpha1-4)Gal(beta1-4)Glc] and 3'-sialyllactose [Neu5Ac(alpha2-3)Gal(beta1-4)Glc] have been prepared by improved routes.
T3 392-570 Sentence denotes The 2-bromoethyl glycosides were then used in cesium carbonate promoted alkylations of the sulfhydryl groups of cysteine and homocysteine residues in T cell stimulating peptides.
T4 571-712 Sentence denotes This convergent and general approach was used to prepare 16 neoglycopeptides which were obtained in 52-95% yields after purification by HPLC.
T5 713-850 Sentence denotes 1H NMR spectroscopy revealed that beta-elimination and epimerization of neoglycopeptide stereocentres did not occur during the synthesis.

GlyCosmos6-Glycan-Motif-Structure

Id Subject Object Predicate Lexical cue
T1 203-212 https://glytoucan.org/Structures/Glycans/G62763GO denotes galabiose
T2 320-326 https://glytoucan.org/Structures/Glycans/G81533KY denotes Neu5Ac

GlyCosmos15-Glycan

Id Subject Object Predicate Lexical cue image
T1 320-326 Glycan denotes Neu5Ac https://api.glycosmos.org/wurcs2image/latest/png/binary/G76685HR

Glycan-GlyCosmos

Id Subject Object Predicate Lexical cue image
T1 320-326 Glycan denotes Neu5Ac https://api.glycosmos.org/wurcs2image/latest/png/binary/G76685HR

GlyCosmos15-CL

Id Subject Object Predicate Lexical cue cl_id
T1 121-127 Cell denotes T cell http://purl.obolibrary.org/obo/CL:0000084
T2 542-548 Cell denotes T cell http://purl.obolibrary.org/obo/CL:0000084

GlyCosmos15-UBERON

Id Subject Object Predicate Lexical cue uberon_id
T1 121-127 Body_part denotes T cell http://purl.obolibrary.org/obo/CL_0000084
T2 542-548 Body_part denotes T cell http://purl.obolibrary.org/obo/CL_0000084

GlyCosmos15-Sentences

Id Subject Object Predicate Lexical cue
T1 0-149 Sentence denotes Convergent synthesis of neoglycopeptides by coupling of 2-bromoethyl glycosides to cysteine and homocysteine residues in T cell stimulating peptides.
T2 150-391 Sentence denotes The 2-bromoethyl beta-glycosides of the disaccharide galabiose [Gal(alpha1-4)Gal] and the trisaccharides globotriose [Gal(alpha1-4)Gal(beta1-4)Glc] and 3'-sialyllactose [Neu5Ac(alpha2-3)Gal(beta1-4)Glc] have been prepared by improved routes.
T3 392-570 Sentence denotes The 2-bromoethyl glycosides were then used in cesium carbonate promoted alkylations of the sulfhydryl groups of cysteine and homocysteine residues in T cell stimulating peptides.
T4 571-712 Sentence denotes This convergent and general approach was used to prepare 16 neoglycopeptides which were obtained in 52-95% yields after purification by HPLC.
T5 713-850 Sentence denotes 1H NMR spectroscopy revealed that beta-elimination and epimerization of neoglycopeptide stereocentres did not occur during the synthesis.

Anatomy-UBERON

Id Subject Object Predicate Lexical cue uberon_id
T1 121-127 Body_part denotes T cell http://purl.obolibrary.org/obo/CL_0000084
T2 542-548 Body_part denotes T cell http://purl.obolibrary.org/obo/CL_0000084

CL-cell

Id Subject Object Predicate Lexical cue cl_id
T1 121-127 Cell denotes T cell http://purl.obolibrary.org/obo/CL:0000084
T2 542-548 Cell denotes T cell http://purl.obolibrary.org/obo/CL:0000084