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PubMed:3378230 JSONTXT

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sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-96 Sentence denotes Synthesis of a close analog of the repeating unit of the antifreeze glycoproteins of polar fish.
TextSentencer_T2 97-397 Sentence denotes The protected glycopeptide N-(benzyloxycarbonyl)-L-alanyl-[O-(2,3,4,6-tetra-O-benzoyl-beta-D- galactopyranosyl)-(1----3)-O-(2,4,6-tri-O-benzyl-alpha-D-galactopyranosy l)- (1----3)]-L-threonyl-L-alanine 2,2,2-trichloroethyl ester was made by coupling the respective disaccharide and tripeptide blocks.
TextSentencer_T3 398-754 Sentence denotes The disaccharide block was generated by coupling tetra-O-benzoyl-alpha-D-galactopyranosyl bromide to allyl 2,4,6-tri-O-benzyl-alpha-D-galactopyranoside and converting the product into O-(2,3,4,6-tetra-O-benzoyl-beta-D-galactopyranosyl)-(1----3)-2,4,6-tri-O -benzyl - alpha-D-galactopyranosyl chloride via the 1-propenyl glycoside and the free (1-OH) sugar.
TextSentencer_T4 755-934 Sentence denotes Alternatively, the 1-propenyl intermediate was obtained directly by using 1-propenyl 2,4,6-tri-O-benzyl-alpha-D-galactopyranoside as the acceptor in the initial coupling reaction.
TextSentencer_T5 935-1169 Sentence denotes An efficient 3-step synthesis of 10 was accomplished by the dibutyltin oxide-assisted, selective crotylation of allyl alpha-D-galactopyranoside at O-3, followed by benzylation and treatment of the product with potassium tert-butoxide.
TextSentencer_T6 1170-1320 Sentence denotes The N-benzyloxycarbonyl (Z) and N-tert-butoxycarbonyl (Boc) 2,2,2-trichloroethyl esters of Thr-Ala and Ala-Thr-Ala were formed by sequential coupling.
TextSentencer_T7 1321-1546 Sentence denotes The silver triflate-promoted glycosylation of the Z-protected dipeptide and tripeptide by 2,3,4,6-tetra-O-benzyl-alpha-D-galactopyranosyl chloride, and of the tripeptide by 6, proceeded with excellent alpha-stereoselectivity.
TextSentencer_T8 1547-1657 Sentence denotes From the disaccharide tripeptide 21, the carboxyl-deprotected and fully deprotected derivatives were prepared.
T1 0-96 Sentence denotes Synthesis of a close analog of the repeating unit of the antifreeze glycoproteins of polar fish.
T2 97-397 Sentence denotes The protected glycopeptide N-(benzyloxycarbonyl)-L-alanyl-[O-(2,3,4,6-tetra-O-benzoyl-beta-D- galactopyranosyl)-(1----3)-O-(2,4,6-tri-O-benzyl-alpha-D-galactopyranosy l)- (1----3)]-L-threonyl-L-alanine 2,2,2-trichloroethyl ester was made by coupling the respective disaccharide and tripeptide blocks.
T3 398-754 Sentence denotes The disaccharide block was generated by coupling tetra-O-benzoyl-alpha-D-galactopyranosyl bromide to allyl 2,4,6-tri-O-benzyl-alpha-D-galactopyranoside and converting the product into O-(2,3,4,6-tetra-O-benzoyl-beta-D-galactopyranosyl)-(1----3)-2,4,6-tri-O -benzyl - alpha-D-galactopyranosyl chloride via the 1-propenyl glycoside and the free (1-OH) sugar.
T4 755-934 Sentence denotes Alternatively, the 1-propenyl intermediate was obtained directly by using 1-propenyl 2,4,6-tri-O-benzyl-alpha-D-galactopyranoside as the acceptor in the initial coupling reaction.
T5 935-1169 Sentence denotes An efficient 3-step synthesis of 10 was accomplished by the dibutyltin oxide-assisted, selective crotylation of allyl alpha-D-galactopyranoside at O-3, followed by benzylation and treatment of the product with potassium tert-butoxide.
T6 1170-1320 Sentence denotes The N-benzyloxycarbonyl (Z) and N-tert-butoxycarbonyl (Boc) 2,2,2-trichloroethyl esters of Thr-Ala and Ala-Thr-Ala were formed by sequential coupling.
T7 1321-1546 Sentence denotes The silver triflate-promoted glycosylation of the Z-protected dipeptide and tripeptide by 2,3,4,6-tetra-O-benzyl-alpha-D-galactopyranosyl chloride, and of the tripeptide by 6, proceeded with excellent alpha-stereoselectivity.
T8 1547-1657 Sentence denotes From the disaccharide tripeptide 21, the carboxyl-deprotected and fully deprotected derivatives were prepared.

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 91-95 OrganismTaxon denotes fish 117565|117569|118072|7777|7878|7898
T7 167-174 OrganismTaxon denotes tetra-O 100829
T8 447-454 OrganismTaxon denotes tetra-O 100829
T9 593-600 OrganismTaxon denotes tetra-O 100829
T10 1419-1426 OrganismTaxon denotes tetra-O 100829