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PubMed:2620298 JSONTXT

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sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-88 Sentence denotes Stereoselective synthesis of 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides).
TextSentencer_T2 89-235 Sentence denotes The synthesis is described of highly acid-sensitive, 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides) as potential anti-cancer prodrugs.
TextSentencer_T3 236-641 Sentence denotes Reaction of 2,3,4,6-tetra-O-acetyl-1-O-trimethylsilyl-beta-D-glucopyranose (4) severally with various aliphatic and alicyclic ketones and methyl trimethylsilyl ether, in the presence of catalytic amounts of trimethylsilyl trifluoromethanesulfonate, afforded the corresponding acetylated acetal-beta-glucosides, e.g., acetone gave 1-methoxy-1-methylethyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside (7a).
TextSentencer_T4 642-719 Sentence denotes Likewise the alpha-anomer (8a) of 7a was obtained from the alpha-anomer of 4.
TextSentencer_T5 720-805 Sentence denotes Deacetylation of the tetra-acetates then gave the acetal-alpha- and -beta-glucosides.
T1 0-88 Sentence denotes Stereoselective synthesis of 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides).
T2 89-235 Sentence denotes The synthesis is described of highly acid-sensitive, 1,1-dialkyl-1-methoxymethyl glucosides (acetal-glucosides) as potential anti-cancer prodrugs.
T3 236-641 Sentence denotes Reaction of 2,3,4,6-tetra-O-acetyl-1-O-trimethylsilyl-beta-D-glucopyranose (4) severally with various aliphatic and alicyclic ketones and methyl trimethylsilyl ether, in the presence of catalytic amounts of trimethylsilyl trifluoromethanesulfonate, afforded the corresponding acetylated acetal-beta-glucosides, e.g., acetone gave 1-methoxy-1-methylethyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside (7a).
T4 642-719 Sentence denotes Likewise the alpha-anomer (8a) of 7a was obtained from the alpha-anomer of 4.
T5 720-805 Sentence denotes Deacetylation of the tetra-acetates then gave the acetal-alpha- and -beta-glucosides.

PubmedHPO

Id Subject Object Predicate Lexical cue
T1 219-225 HP_0002664 denotes cancer

mondo_disease

Id Subject Object Predicate Lexical cue mondo_id
T1 219-225 Disease denotes cancer http://purl.obolibrary.org/obo/MONDO_0004992

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 256-263 OrganismTaxon denotes tetra-O 100829
T2 598-605 OrganismTaxon denotes tetra-O 100829

HP-phenotype

Id Subject Object Predicate Lexical cue hp_id
T1 219-225 Phenotype denotes cancer HP:0002664