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PubMed:24957577 JSONTXT

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sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-82 Sentence denotes NMR characterization of chemically synthesized branched α-dextrin model compounds.
TextSentencer_T2 83-248 Sentence denotes 1H and 13C NMR chemical shifts were accurately determined by consistent referencing for an extensive set of chemically synthesized branched α-glucan model compounds.
TextSentencer_T3 249-394 Sentence denotes The model compounds include anomerically fixed and reducing oligosaccharides ranging in size from isomaltose to a doubly branched decasaccharide.
TextSentencer_T4 395-669 Sentence denotes Both the 13C1 chemical shift and the 13C6 chemical shifts in α-(1→6) glycosidic bonds are strongly dependent on the chemical structure in the vicinity of the branch point, especially on the addition of glucopyranosyl units towards the non-reducing end of the backbone chain.
TextSentencer_T5 670-820 Sentence denotes The conformational sampling at the branch point of the branched α-glucan model compounds was experimentally probed with homo-nuclear scalar couplings.
TextSentencer_T6 821-983 Sentence denotes Substitution at O6 consistently increases the fraction of C6-O6 trans conformations, but to a lesser extent, if the attachment occurs at the reducing end residue.
TextSentencer_T7 984-1127 Sentence denotes Increasingly complex structures in the vicinity of the branch point increase the population of the gauche-trans conformation of the C5-C6 bond.
TextSentencer_T8 1128-1202 Sentence denotes This population change is found to correlate with the 13C6 chemical shift.
T1 0-82 Sentence denotes NMR characterization of chemically synthesized branched α-dextrin model compounds.
T2 83-248 Sentence denotes 1H and 13C NMR chemical shifts were accurately determined by consistent referencing for an extensive set of chemically synthesized branched α-glucan model compounds.
T3 249-394 Sentence denotes The model compounds include anomerically fixed and reducing oligosaccharides ranging in size from isomaltose to a doubly branched decasaccharide.
T4 395-669 Sentence denotes Both the 13C1 chemical shift and the 13C6 chemical shifts in α-(1→6) glycosidic bonds are strongly dependent on the chemical structure in the vicinity of the branch point, especially on the addition of glucopyranosyl units towards the non-reducing end of the backbone chain.
T5 670-820 Sentence denotes The conformational sampling at the branch point of the branched α-glucan model compounds was experimentally probed with homo-nuclear scalar couplings.
T6 821-983 Sentence denotes Substitution at O6 consistently increases the fraction of C6-O6 trans conformations, but to a lesser extent, if the attachment occurs at the reducing end residue.
T7 984-1127 Sentence denotes Increasingly complex structures in the vicinity of the branch point increase the population of the gauche-trans conformation of the C5-C6 bond.
T8 1128-1202 Sentence denotes This population change is found to correlate with the 13C6 chemical shift.

GlyCosmos15-Glycan

Id Subject Object Predicate Lexical cue image
T1 347-357 Glycan denotes isomaltose https://api.glycosmos.org/wurcs2image/latest/png/binary/G36281WI

Glycan-GlyCosmos

Id Subject Object Predicate Lexical cue image
T1 347-357 Glycan denotes isomaltose https://api.glycosmos.org/wurcs2image/latest/png/binary/G36281WI

GlyCosmos15-UBERON

Id Subject Object Predicate Lexical cue uberon_id
T1 654-662 Body_part denotes backbone http://purl.obolibrary.org/obo/UBERON_0001130

GlyCosmos15-Sentences

Id Subject Object Predicate Lexical cue
T1 0-82 Sentence denotes NMR characterization of chemically synthesized branched α-dextrin model compounds.
T2 83-248 Sentence denotes 1H and 13C NMR chemical shifts were accurately determined by consistent referencing for an extensive set of chemically synthesized branched α-glucan model compounds.
T3 249-394 Sentence denotes The model compounds include anomerically fixed and reducing oligosaccharides ranging in size from isomaltose to a doubly branched decasaccharide.
T4 395-669 Sentence denotes Both the 13C1 chemical shift and the 13C6 chemical shifts in α-(1→6) glycosidic bonds are strongly dependent on the chemical structure in the vicinity of the branch point, especially on the addition of glucopyranosyl units towards the non-reducing end of the backbone chain.
T5 670-820 Sentence denotes The conformational sampling at the branch point of the branched α-glucan model compounds was experimentally probed with homo-nuclear scalar couplings.
T6 821-983 Sentence denotes Substitution at O6 consistently increases the fraction of C6-O6 trans conformations, but to a lesser extent, if the attachment occurs at the reducing end residue.
T7 984-1127 Sentence denotes Increasingly complex structures in the vicinity of the branch point increase the population of the gauche-trans conformation of the C5-C6 bond.
T8 1128-1202 Sentence denotes This population change is found to correlate with the 13C6 chemical shift.

GlyCosmos15-FMA

Id Subject Object Predicate Lexical cue db_id
T1 654-662 Body_part denotes backbone FMA:13478

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 790-794 OrganismTaxon denotes homo 9605

Anatomy-UBERON

Id Subject Object Predicate Lexical cue uberon_id
T1 654-662 Body_part denotes backbone http://purl.obolibrary.org/obo/UBERON_0001130