| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-142 |
Sentence |
denotes |
Monomer sequence determination of carbohydrates using fast-atom bombardment mass spectrometry of periodate-oxidized acetate ester derivatives. |
| TextSentencer_T2 |
143-207 |
Sentence |
denotes |
A derivatization method, adapted from that of Angel et al. (ref. |
| TextSentencer_T3 |
208-337 |
Sentence |
denotes |
10), for sequencing sugar residues in partially degraded poly- and oligo-saccharides using positive-ion f.a.b.-m.s. is described. |
| TextSentencer_T4 |
338-551 |
Sentence |
denotes |
Derivative selection provides sequence information by directing fragmentation exclusively to both sides of glycosidic oxygen atoms and, in the case of opened rings, between glycosidic carbon and ring oxygen atoms. |
| TextSentencer_T5 |
552-678 |
Sentence |
denotes |
Polysaccharides or oligosaccharides are subjected to sequential periodate oxidation, borodeuteride reduction, and acetylation. |
| TextSentencer_T6 |
679-834 |
Sentence |
denotes |
The derivatized polysaccharides are then subjected to partial degradation, acetylation, and high-performance liquid chromatography (h.p.l.c.) purification. |
| TextSentencer_T7 |
835-1110 |
Sentence |
denotes |
F.a.b.-m.s. data obtained on model compounds, using 3-nitrobenzyl alcohol as matrix for f.a.b.-m.s., demonstrated direction of fragmentation to both sides of the glycosidic oxygen atom in unoxidized residues, and to both sides of the acetal oxygen atoms in oxidized residues. |
| TextSentencer_T8 |
1111-1259 |
Sentence |
denotes |
Oligosaccharide linkage and sequence may thus be determined by observing fragmentation from both the reducing and non-reducing ends of the molecule. |
| TextSentencer_T9 |
1260-1373 |
Sentence |
denotes |
Two Salmonella lipopolysaccharides, derivatized by this procedure, were partially hydrolyzed and then acetylated. |
| TextSentencer_T10 |
1374-1553 |
Sentence |
denotes |
Analysis of the h.p.l.c.-purified oligosaccharide derivatives by f.a.b.-m.s. demonstrated the applicability of the technique for sequencing nmol quantities of branched structures. |
| T1 |
0-142 |
Sentence |
denotes |
Monomer sequence determination of carbohydrates using fast-atom bombardment mass spectrometry of periodate-oxidized acetate ester derivatives. |
| T2 |
143-207 |
Sentence |
denotes |
A derivatization method, adapted from that of Angel et al. (ref. |
| T3 |
208-337 |
Sentence |
denotes |
10), for sequencing sugar residues in partially degraded poly- and oligo-saccharides using positive-ion f.a.b.-m.s. is described. |
| T4 |
338-551 |
Sentence |
denotes |
Derivative selection provides sequence information by directing fragmentation exclusively to both sides of glycosidic oxygen atoms and, in the case of opened rings, between glycosidic carbon and ring oxygen atoms. |
| T5 |
552-678 |
Sentence |
denotes |
Polysaccharides or oligosaccharides are subjected to sequential periodate oxidation, borodeuteride reduction, and acetylation. |
| T6 |
679-834 |
Sentence |
denotes |
The derivatized polysaccharides are then subjected to partial degradation, acetylation, and high-performance liquid chromatography (h.p.l.c.) purification. |
| T7 |
835-1110 |
Sentence |
denotes |
F.a.b.-m.s. data obtained on model compounds, using 3-nitrobenzyl alcohol as matrix for f.a.b.-m.s., demonstrated direction of fragmentation to both sides of the glycosidic oxygen atom in unoxidized residues, and to both sides of the acetal oxygen atoms in oxidized residues. |
| T8 |
1111-1259 |
Sentence |
denotes |
Oligosaccharide linkage and sequence may thus be determined by observing fragmentation from both the reducing and non-reducing ends of the molecule. |
| T9 |
1260-1373 |
Sentence |
denotes |
Two Salmonella lipopolysaccharides, derivatized by this procedure, were partially hydrolyzed and then acetylated. |
| T10 |
1374-1553 |
Sentence |
denotes |
Analysis of the h.p.l.c.-purified oligosaccharide derivatives by f.a.b.-m.s. demonstrated the applicability of the technique for sequencing nmol quantities of branched structures. |