PubMed:21920515 JSONTXT

{"project":"sentences","denotations":[{"id":"TextSentencer_T1","span":{"begin":0,"end":117},"obj":"Sentence"},{"id":"TextSentencer_T2","span":{"begin":118,"end":610},"obj":"Sentence"},{"id":"TextSentencer_T3","span":{"begin":611,"end":730},"obj":"Sentence"},{"id":"TextSentencer_T4","span":{"begin":731,"end":928},"obj":"Sentence"},{"id":"TextSentencer_T5","span":{"begin":929,"end":1056},"obj":"Sentence"},{"id":"TextSentencer_T6","span":{"begin":1057,"end":1131},"obj":"Sentence"},{"id":"TextSentencer_T7","span":{"begin":1132,"end":1281},"obj":"Sentence"},{"id":"TextSentencer_T8","span":{"begin":1282,"end":1412},"obj":"Sentence"},{"id":"T1","span":{"begin":0,"end":117},"obj":"Sentence"},{"id":"T2","span":{"begin":118,"end":610},"obj":"Sentence"},{"id":"T3","span":{"begin":611,"end":730},"obj":"Sentence"},{"id":"T4","span":{"begin":731,"end":928},"obj":"Sentence"},{"id":"T5","span":{"begin":929,"end":1056},"obj":"Sentence"},{"id":"T6","span":{"begin":1057,"end":1131},"obj":"Sentence"},{"id":"T7","span":{"begin":1132,"end":1281},"obj":"Sentence"},{"id":"T8","span":{"begin":1282,"end":1412},"obj":"Sentence"}],"namespaces":[{"prefix":"_base","uri":"http://pubannotation.org/ontology/tao.owl#"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

{"project":"GlyCosmos600-FMA","denotations":[{"id":"T1","span":{"begin":128,"end":143},"obj":"Body_part"},{"id":"T2","span":{"begin":611,"end":622},"obj":"Body_part"},{"id":"T3","span":{"begin":818,"end":830},"obj":"Body_part"},{"id":"T4","span":{"begin":1156,"end":1168},"obj":"Body_part"}],"attributes":[{"id":"A1","pred":"fma_id","subj":"T1","obj":"http://purl.org/sig/ont/fma/fma82742"},{"id":"A2","pred":"fma_id","subj":"T2","obj":"http://purl.org/sig/ont/fma/fma82797"},{"id":"A3","pred":"fma_id","subj":"T3","obj":"http://purl.org/sig/ont/fma/fma82744"},{"id":"A4","pred":"fma_id","subj":"T4","obj":"http://purl.org/sig/ont/fma/fma82744"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

{"project":"glycosmos-test-glycan-structure","denotations":[{"id":"PD-GlycanStructures-B_T1","span":{"begin":611,"end":622},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa208/trivialname"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

{"project":"glycosmos-test-structure-v1","denotations":[{"id":"PD-GlycanStructures-B_T1","span":{"begin":611,"end":622},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa208/trivialname"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

{"project":"GlyCosmos600-GlycoProteins","denotations":[{"id":"PD-GlycoProteins-B_T1","span":{"begin":84,"end":87},"obj":"http://purl.uniprot.org/uniprot/P06744"},{"id":"PD-GlycoProteins-B_T2","span":{"begin":342,"end":345},"obj":"http://purl.uniprot.org/uniprot/P06744"},{"id":"PD-GlycoProteins-B_T3","span":{"begin":1388,"end":1391},"obj":"http://purl.uniprot.org/uniprot/P06744"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

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EnjuParser_T171","obj":"EnjuParser_T178"},{"id":"EnjuParser_R182","pred":"arg1Of","subj":"EnjuParser_T182","obj":"EnjuParser_T179"},{"id":"EnjuParser_R183","pred":"arg1Of","subj":"EnjuParser_T182","obj":"EnjuParser_T180"},{"id":"EnjuParser_R184","pred":"arg1Of","subj":"EnjuParser_T182","obj":"EnjuParser_T181"},{"id":"EnjuParser_R185","pred":"arg1Of","subj":"EnjuParser_T182","obj":"EnjuParser_T183"},{"id":"EnjuParser_R186","pred":"arg1Of","subj":"EnjuParser_T188","obj":"EnjuParser_T184"},{"id":"EnjuParser_R187","pred":"arg1Of","subj":"EnjuParser_T185","obj":"EnjuParser_T186"},{"id":"EnjuParser_R188","pred":"arg2Of","subj":"EnjuParser_T187","obj":"EnjuParser_T186"},{"id":"EnjuParser_R189","pred":"arg1Of","subj":"EnjuParser_T186","obj":"EnjuParser_T188"},{"id":"EnjuParser_R190","pred":"arg2Of","subj":"EnjuParser_T189","obj":"EnjuParser_T188"},{"id":"EnjuParser_R191","pred":"arg1Of","subj":"EnjuParser_T188","obj":"EnjuParser_T190"},{"id":"EnjuParser_R192","pred":"arg2Of","subj":"EnjuParser_T192","obj":"EnjuParser_T190"},{"id":"EnjuParser_R193","pred":"arg1Of","subj":"EnjuParser_T192","obj":"EnjuParser_T191"},{"id":"EnjuParser_R194","pred":"arg1Of","subj":"EnjuParser_T192","obj":"EnjuParser_T193"},{"id":"EnjuParser_R195","pred":"arg2Of","subj":"EnjuParser_T194","obj":"EnjuParser_T193"},{"id":"EnjuParser_R196","pred":"arg2Of","subj":"EnjuParser_T198","obj":"EnjuParser_T194"},{"id":"EnjuParser_R197","pred":"arg1Of","subj":"EnjuParser_T198","obj":"EnjuParser_T195"},{"id":"EnjuParser_R198","pred":"arg1Of","subj":"EnjuParser_T198","obj":"EnjuParser_T196"},{"id":"EnjuParser_R199","pred":"arg1Of","subj":"EnjuParser_T198","obj":"EnjuParser_T197"},{"id":"EnjuParser_R200","pred":"arg1Of","subj":"EnjuParser_T198","obj":"EnjuParser_T199"},{"id":"EnjuParser_R201","pred":"arg2Of","subj":"EnjuParser_T202","obj":"EnjuParser_T199"},{"id":"EnjuParser_R202","pred":"arg1Of","subj":"EnjuParser_T202","obj":"EnjuParser_T200"},{"id":"EnjuParser_R203","pred":"arg1Of","subj":"EnjuParser_T202","obj":"EnjuParser_T201"},{"id":"EnjuParser_R204","pred":"arg1Of","subj":"EnjuParser_T202","obj":"EnjuParser_T203"},{"id":"EnjuParser_R205","pred":"arg2Of","subj":"EnjuParser_T205","obj":"EnjuParser_T203"},{"id":"EnjuParser_R206","pred":"arg1Of","subj":"EnjuParser_T205","obj":"EnjuParser_T204"}],"namespaces":[{"prefix":"_base","uri":"http://kmcs.nii.ac.jp/enju/"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}

{"project":"NCBITAXON","denotations":[{"id":"T1","span":{"begin":98,"end":116},"obj":"OrganismTaxon"},{"id":"T2","span":{"begin":356,"end":374},"obj":"OrganismTaxon"},{"id":"T3","span":{"begin":662,"end":669},"obj":"OrganismTaxon"}],"attributes":[{"id":"A1","pred":"db_id","subj":"T1","obj":"5691"},{"id":"A2","pred":"db_id","subj":"T2","obj":"5691"},{"id":"A3","pred":"db_id","subj":"T3","obj":"100829"}],"text":"Synthesis of octyl S-glycosides of tri- to pentasaccharide fragments related to the GPI anchor of Trypanosoma brucei.\nThe three oligosaccharide octyl-S-glycosides Man-α1,6-Man-α1,4-GlcNH(2)-α1,S-Octyl (19), Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (27) and Man-α1,2-Man-α1,6-(Gal-α1,3)Man-α1,4-GlcNH(2)-α1,S-Octyl (37), related to the GPI anchor of Trypanosoma brucei were prepared by a stepwise and block-wise approach from octyl 2-azido-2-deoxy-3,6-di-O-benzyl-1-thio-α-D-glucopyranoside (8) and octyl 2-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-1-thio-α-D-mannopyransoside (9). Glucosamine derivative 8 was obtained from 1,3,4,6-tetra-O-acetyl-2-azido-2-desoxy-β-D-glucopyranose (1) in five steps. Mannoside 9 was converted into the corresponding imidate 12 and coupled with 8 to give disaccharide octyl-S-glycoside 13 which was further mannosylated to afford trisaccharide 19 upon deprotection. Likewise, mannoside 9 was galactosylated, converted into the corresponding imidate and coupled with 8 to give trisaccharide 25. Mannosylation of the latter afforded tetrasaccharide 27 upon deprotection. Condensation of 25 with disaccharide imidate 35 gave, upon deprotection of the intermediates, the corresponding pentasaccharide octyl-S-glycoside 37. Saccharides 19, 27 and 37 are suitable substrates for studying the enzymatic glycosylation pattern of the GPI anchor of T. brucei."}