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PubMed:2171766 JSONTXT

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sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-310 Sentence denotes Use of the methylsulfenyl cation as an activator for glycosylation reactions with alkyl (aryl) 1-thioglycopyranosides: synthesis of methyl O-(2-acetamido-2- deoxy-beta-D-glucopyranosyl)-(1----6)-O-alpha-D-glucopyranosyl-(1----2) -alpha-D -glucopyranoside, a derivative of the core trisaccharide of E. coli K12.
TextSentencer_T2 311-446 Sentence denotes Methylsulfenyl bromide (MSB) and methylsulfenyl trifluoromethanesulfonate (MST) have been used to prepare 1,2-cis-linked disaccharides.
TextSentencer_T3 447-586 Sentence denotes Ethyl (phenyl) 1-thio-beta-D-gluco- and galacto-pyranosides having non-participating (benzyloxy) protecting groups were used as the donors.
TextSentencer_T4 587-676 Sentence denotes The alpha beta-ratio of the products depended on the promoter and conditions of reaction.
TextSentencer_T5 677-779 Sentence denotes Intimate ion-pairs, formed initially, may be responsible for the steric outcome of the glycosylations.
TextSentencer_T6 780-953 Sentence denotes Thus, with ethyl 2,3,4,6-tetra-O-benzyl-alpha-D-mannopyranoside as a donor, moderate quantities of the beta-linked disaccharide could be produced using MSB as the activator.
TextSentencer_T7 954-1063 Sentence denotes The synthesis of the title trisaccharide glycoside that contains 1,2-cis and 1,2-trans-linkages is described.
T1 0-310 Sentence denotes Use of the methylsulfenyl cation as an activator for glycosylation reactions with alkyl (aryl) 1-thioglycopyranosides: synthesis of methyl O-(2-acetamido-2- deoxy-beta-D-glucopyranosyl)-(1----6)-O-alpha-D-glucopyranosyl-(1----2) -alpha-D -glucopyranoside, a derivative of the core trisaccharide of E. coli K12.
T2 311-446 Sentence denotes Methylsulfenyl bromide (MSB) and methylsulfenyl trifluoromethanesulfonate (MST) have been used to prepare 1,2-cis-linked disaccharides.
T3 447-586 Sentence denotes Ethyl (phenyl) 1-thio-beta-D-gluco- and galacto-pyranosides having non-participating (benzyloxy) protecting groups were used as the donors.
T4 587-676 Sentence denotes The alpha beta-ratio of the products depended on the promoter and conditions of reaction.
T5 677-779 Sentence denotes Intimate ion-pairs, formed initially, may be responsible for the steric outcome of the glycosylations.
T6 780-953 Sentence denotes Thus, with ethyl 2,3,4,6-tetra-O-benzyl-alpha-D-mannopyranoside as a donor, moderate quantities of the beta-linked disaccharide could be produced using MSB as the activator.
T7 954-1063 Sentence denotes The synthesis of the title trisaccharide glycoside that contains 1,2-cis and 1,2-trans-linkages is described.

mondo_disease

Id Subject Object Predicate Lexical cue mondo_id
T1 386-389 Disease denotes MST http://purl.obolibrary.org/obo/MONDO_0008040

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 298-305 OrganismTaxon denotes E. coli 562
T2 805-812 OrganismTaxon denotes tetra-O 100829