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PubMed:2136384 JSONTXT

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GlycoBiology-FMA

Id Subject Object Predicate Lexical cue
_T1 50-56 FMAID:196724 denotes sugars
_T2 60-76 FMAID:196731 denotes oligosaccharides
_T3 60-76 FMAID:82742 denotes oligosaccharides
_T4 266-272 FMAID:196724 denotes sugars
_T5 276-292 FMAID:196731 denotes oligosaccharides
_T6 276-292 FMAID:82742 denotes oligosaccharides
_T7 362-378 FMAID:82742 denotes oligosaccharides
_T8 362-378 FMAID:196731 denotes oligosaccharides
_T9 533-545 FMAID:82737 denotes carbohydrate
_T10 533-545 FMAID:197276 denotes carbohydrate
_T11 1248-1263 FMAID:82785 denotes polysaccharides
_T12 1248-1263 FMAID:196779 denotes polysaccharides
_T13 1248-1263 FMAID:196735 denotes polysaccharides
_T14 1248-1263 FMAID:82746 denotes polysaccharides
_T15 1383-1396 FMAID:82737 denotes carbohydrates
_T16 1383-1396 FMAID:197276 denotes carbohydrates

uniprot-human

Id Subject Object Predicate Lexical cue
T1 99-101 http://www.uniprot.org/uniprot/Q99707 denotes MS
T2 209-211 http://www.uniprot.org/uniprot/Q99707 denotes MS
T3 398-400 http://www.uniprot.org/uniprot/Q99707 denotes MS
T4 864-866 http://www.uniprot.org/uniprot/Q99707 denotes MS
T5 1100-1102 http://www.uniprot.org/uniprot/Q99707 denotes MS
T6 1284-1286 http://www.uniprot.org/uniprot/Q99707 denotes MS

uniprot-mouse

Id Subject Object Predicate Lexical cue
T1 99-101 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS
T2 209-211 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS
T3 398-400 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS
T4 864-866 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS
T5 1100-1102 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS
T6 1284-1286 http://www.uniprot.org/uniprot/A6H5Y3 denotes MS

GlycoBiology-NCBITAXON

Id Subject Object Predicate Lexical cue
T1 657-661 http://purl.bioontology.org/ontology/NCBITAXON/3554 denotes beta
T2 657-661 http://purl.bioontology.org/ontology/NCBITAXON/158455 denotes beta

sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-111 Sentence denotes Assignment of anomeric configurations of pyranose sugars in oligosaccharides using a sensitive FAB-MS strategy.
TextSentencer_T2 112-293 Sentence denotes This paper describes a sensitive strategy employing fast atom bombardment mass spectrometry (FAB-MS) for defining the anomeric configurations of pyranose sugars in oligosaccharides.
TextSentencer_T3 294-493 Sentence denotes The method, which is applicable to mixtures of reduced or unreduced oligosaccharides, is based upon FAB-MS analyses of deuteroacetylated derivatives before and after oxidation with chromium trioxide.
TextSentencer_T4 494-730 Sentence denotes This reagent, whose potential value in carbohydrate chemistry was first recognized by Angyal and which was subsequently more fully exploited by Lindberg, oxidizes beta-pyranosides to keto-esters leaving alpha-pyranosides largely intact.
TextSentencer_T5 731-867 Sentence denotes In this paper we show that the products of chromium trioxide oxidation can be successfully analysed at the microgram level using FAB-MS.
TextSentencer_T6 868-1002 Sentence denotes The molecular and fragment ions produced in the FAB experiment define the number of sites oxidized and their location in the sequence.
TextSentencer_T7 1003-1172 Sentence denotes For samples which fragment poorly we describe a mild methanolysis procedure, compatible with FAB-MS, which preferentially cleaves the esters formed during the oxidation.
TextSentencer_T8 1173-1264 Sentence denotes Incorporation of an acetolysis step prior to oxidation permits analyses of polysaccharides.
TextSentencer_T9 1265-1492 Sentence denotes This oxidation/FAB-MS strategy should prove valuable in structural analyses of a wide range of biologically important carbohydrates which cannot be isolated in sufficient quantities to permit nuclear magnetic resonance studies.
T1 0-111 Sentence denotes Assignment of anomeric configurations of pyranose sugars in oligosaccharides using a sensitive FAB-MS strategy.
T2 112-293 Sentence denotes This paper describes a sensitive strategy employing fast atom bombardment mass spectrometry (FAB-MS) for defining the anomeric configurations of pyranose sugars in oligosaccharides.
T3 294-493 Sentence denotes The method, which is applicable to mixtures of reduced or unreduced oligosaccharides, is based upon FAB-MS analyses of deuteroacetylated derivatives before and after oxidation with chromium trioxide.
T4 494-730 Sentence denotes This reagent, whose potential value in carbohydrate chemistry was first recognized by Angyal and which was subsequently more fully exploited by Lindberg, oxidizes beta-pyranosides to keto-esters leaving alpha-pyranosides largely intact.
T5 731-867 Sentence denotes In this paper we show that the products of chromium trioxide oxidation can be successfully analysed at the microgram level using FAB-MS.
T6 868-1002 Sentence denotes The molecular and fragment ions produced in the FAB experiment define the number of sites oxidized and their location in the sequence.
T7 1003-1172 Sentence denotes For samples which fragment poorly we describe a mild methanolysis procedure, compatible with FAB-MS, which preferentially cleaves the esters formed during the oxidation.
T8 1173-1264 Sentence denotes Incorporation of an acetolysis step prior to oxidation permits analyses of polysaccharides.
T9 1265-1492 Sentence denotes This oxidation/FAB-MS strategy should prove valuable in structural analyses of a wide range of biologically important carbohydrates which cannot be isolated in sufficient quantities to permit nuclear magnetic resonance studies.
T1 0-111 Sentence denotes Assignment of anomeric configurations of pyranose sugars in oligosaccharides using a sensitive FAB-MS strategy.
T2 112-293 Sentence denotes This paper describes a sensitive strategy employing fast atom bombardment mass spectrometry (FAB-MS) for defining the anomeric configurations of pyranose sugars in oligosaccharides.
T3 294-493 Sentence denotes The method, which is applicable to mixtures of reduced or unreduced oligosaccharides, is based upon FAB-MS analyses of deuteroacetylated derivatives before and after oxidation with chromium trioxide.
T4 494-730 Sentence denotes This reagent, whose potential value in carbohydrate chemistry was first recognized by Angyal and which was subsequently more fully exploited by Lindberg, oxidizes beta-pyranosides to keto-esters leaving alpha-pyranosides largely intact.
T5 731-867 Sentence denotes In this paper we show that the products of chromium trioxide oxidation can be successfully analysed at the microgram level using FAB-MS.
T6 868-1002 Sentence denotes The molecular and fragment ions produced in the FAB experiment define the number of sites oxidized and their location in the sequence.
T7 1003-1172 Sentence denotes For samples which fragment poorly we describe a mild methanolysis procedure, compatible with FAB-MS, which preferentially cleaves the esters formed during the oxidation.
T8 1173-1264 Sentence denotes Incorporation of an acetolysis step prior to oxidation permits analyses of polysaccharides.
T9 1265-1492 Sentence denotes This oxidation/FAB-MS strategy should prove valuable in structural analyses of a wide range of biologically important carbohydrates which cannot be isolated in sufficient quantities to permit nuclear magnetic resonance studies.

GO-BP

Id Subject Object Predicate Lexical cue
T1 85-94 http://purl.obolibrary.org/obo/GO_0046960 denotes sensitive
T2 135-144 http://purl.obolibrary.org/obo/GO_0046960 denotes sensitive
T3 164-168 http://purl.obolibrary.org/obo/GO_0033867 denotes fast

EDAM-topics

Id Subject Object Predicate Lexical cue
T1 186-203 http://edamontology.org/topic_0134 denotes mass spectrometry
T2 186-203 http://edamontology.org/topic_3520 denotes mass spectrometry
T3 533-545 http://edamontology.org/topic_0152 denotes carbohydrate
T4 546-555 http://edamontology.org/topic_3314 denotes chemistry
T5 993-1001 http://edamontology.org/topic_3168 denotes sequence
T6 993-1001 http://edamontology.org/topic_0080 denotes sequence
T7 1007-1014 http://edamontology.org/topic_3277 denotes samples
T8 1321-1340 http://edamontology.org/topic_0081 denotes structural analyses
T9 1383-1396 http://edamontology.org/topic_0152 denotes carbohydrates
T10 1457-1483 http://edamontology.org/topic_3444 denotes nuclear magnetic resonance
T11 1484-1491 http://edamontology.org/topic_3678 denotes studies

EDAM-DFO

Id Subject Object Predicate Lexical cue
T1 186-203 http://edamontology.org/data_2536 denotes mass spectrometry
T2 186-203 http://edamontology.org/data_3147 denotes mass spectrometry
T3 993-1001 http://edamontology.org/data_2044 denotes sequence
T4 993-1001 http://edamontology.org/operation_3218 denotes sequence
T5 1321-1331 http://edamontology.org/data_0883 denotes structural
T6 1321-1340 http://edamontology.org/operation_2480 denotes structural analyses

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 1450-1456 OrganismTaxon denotes permit NCBItxid:173331

GlyTouCan-IUPAC

Id Subject Object Predicate Lexical cue
GlycanIUPAC_T1 50-56 "http://rdf.glycoinfo.org/glycan/G59665TO" denotes sugars
GlycanIUPAC_T2 266-272 "http://rdf.glycoinfo.org/glycan/G59665TO" denotes sugars
GlycanIUPAC_T3 50-56 "http://rdf.glycoinfo.org/glycan/G32915EI" denotes sugars
GlycanIUPAC_T4 266-272 "http://rdf.glycoinfo.org/glycan/G32915EI" denotes sugars
GlycanIUPAC_T5 50-56 "http://rdf.glycoinfo.org/glycan/G60625TS" denotes sugars
GlycanIUPAC_T6 266-272 "http://rdf.glycoinfo.org/glycan/G60625TS" denotes sugars