PubMed:20438094 JSONTXT

{"target":"http://pubannotation.org/docs/sourcedb/PubMed/sourceid/20438094","sourcedb":"PubMed","sourceid":"20438094","source_url":"http://www.ncbi.nlm.nih.gov/pubmed/20438094","text":"First structurally characterized tricyanomanganate(III) and its magnetic {Mn(III)(2)M(II)(2)} complexes (M(II) = Mn, Ni).\nTreatment of tris(3-cyano-2,4-pentanedionato)manganese(III) with KTp*, followed by [NEt(4)]CN affords [NEt(4)][(Tp*)Mn(III)(CN)(3)] (1); subsequent treatment of 1 with divalent triflates (OTf) and 2,2'-bipyridine (bpy) affords {Mn(III)(2)M(II)(2)} complexes (M(II) = Mn, 2; Ni, 3). Magnetic measurements show that 1-3 exhibit S(T) = 1, 3, and 4 spin ground states, respectively.","tracks":[{"project":"Allie","denotations":[{"id":"SS1_20438094_1_0","span":{"begin":319,"end":334},"obj":"expanded"},{"id":"SS2_20438094_1_0","span":{"begin":336,"end":339},"obj":"abbr"}],"relations":[{"id":"AE1_20438094_1_0","pred":"abbreviatedTo","subj":"SS1_20438094_1_0","obj":"SS2_20438094_1_0"}],"attributes":[{"subj":"SS1_20438094_1_0","pred":"source","obj":"Allie"},{"subj":"SS2_20438094_1_0","pred":"source","obj":"Allie"}]}],"config":{"attribute types":[{"pred":"source","value type":"selection","values":[{"id":"Allie","color":"#ec93b9","default":true}]}]}}