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PubMed:19187930 JSONTXT

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sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-140 Sentence denotes The first total synthesis of 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl apigenin via a hexanoyl ester-based protection strategy.
TextSentencer_T2 141-374 Sentence denotes The first total synthesis of 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl apigenin 1, which exhibits good anti-hepatitis B virus and anti-stroke activities, was accomplished in six steps and 20% overall yield from apigenin.
TextSentencer_T3 375-546 Sentence denotes Another synthetic route, in which the target was obtained in seven steps, was also developed to prove the utility of a hexanoyl ester-based orthogonal protection strategy.
TextSentencer_T4 547-835 Sentence denotes The hexanoyl protection strategy provided all the flavonoid intermediates with good solubility and reactivity, enabled efficient selective protection and glycosylation, and provided a practical and effective synthetic strategy for flavonoids, starting from commercially available flavone.
T1 0-140 Sentence denotes The first total synthesis of 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl apigenin via a hexanoyl ester-based protection strategy.
T2 141-374 Sentence denotes The first total synthesis of 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl apigenin 1, which exhibits good anti-hepatitis B virus and anti-stroke activities, was accomplished in six steps and 20% overall yield from apigenin.
T3 375-546 Sentence denotes Another synthetic route, in which the target was obtained in seven steps, was also developed to prove the utility of a hexanoyl ester-based orthogonal protection strategy.
T4 547-835 Sentence denotes The hexanoyl protection strategy provided all the flavonoid intermediates with good solubility and reactivity, enabled efficient selective protection and glycosylation, and provided a practical and effective synthetic strategy for flavonoids, starting from commercially available flavone.

pubmed-enju-pas

Id Subject Object Predicate Lexical cue
EnjuParser_T0 0-3 DT denotes The
EnjuParser_T1 4-9 JJ denotes first
EnjuParser_T2 10-15 JJ denotes total
EnjuParser_T3 16-25 NN denotes synthesis
EnjuParser_T4 26-28 IN denotes of
EnjuParser_T5 29-83 NN denotes 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl
EnjuParser_T6 84-92 NN denotes apigenin
EnjuParser_T7 93-96 IN denotes via
EnjuParser_T8 97-98 DT denotes a
EnjuParser_T9 99-107 NN denotes hexanoyl
EnjuParser_T10 108-119 JJ denotes ester-based
EnjuParser_T11 120-130 NN denotes protection
EnjuParser_T12 131-139 NN denotes strategy
EnjuParser_T13 141-144 DT denotes The
EnjuParser_T14 145-150 JJ denotes first
EnjuParser_T15 151-156 JJ denotes total
EnjuParser_T16 157-166 NN denotes synthesis
EnjuParser_T17 167-169 IN denotes of
EnjuParser_T18 170-224 NN denotes 7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl
EnjuParser_T19 225-233 NN denotes apigenin
EnjuParser_T20 234-235 CD denotes 1
EnjuParser_T21 235-236 -COMMA- denotes ,
EnjuParser_T22 237-242 WDT denotes which
EnjuParser_T23 243-251 VBZ denotes exhibits
EnjuParser_T24 252-256 JJ denotes good
EnjuParser_T25 257-271 JJ denotes anti-hepatitis
EnjuParser_T26 272-273 NN denotes B
EnjuParser_T27 274-279 NN denotes virus
EnjuParser_T28 280-283 CC denotes and
EnjuParser_T29 284-295 JJ denotes anti-stroke
EnjuParser_T30 296-306 NNS denotes activities
EnjuParser_T31 306-307 -COMMA- denotes ,
EnjuParser_T32 308-311 VBD denotes was
EnjuParser_T33 312-324 VBN denotes accomplished
EnjuParser_T34 325-327 IN denotes in
EnjuParser_T35 328-331 CD denotes six
EnjuParser_T36 332-337 NNS denotes steps
EnjuParser_T37 338-341 CC denotes and
EnjuParser_T38 342-344 CD denotes 20
EnjuParser_T39 344-345 NN denotes %
EnjuParser_T40 346-353 JJ denotes overall
EnjuParser_T41 354-359 NN denotes yield
EnjuParser_T42 360-364 IN denotes from
EnjuParser_T43 365-373 NN denotes apigenin
EnjuParser_T44 375-382 DT denotes Another
EnjuParser_T45 383-392 JJ denotes synthetic
EnjuParser_T46 393-398 NN denotes route
EnjuParser_T47 398-399 -COMMA- denotes ,
EnjuParser_T48 400-402 IN denotes in
EnjuParser_T49 403-408 WDT denotes which
EnjuParser_T50 409-412 DT denotes the
EnjuParser_T51 413-419 NN denotes target
EnjuParser_T52 420-423 VBD denotes was
EnjuParser_T53 424-432 VBN denotes obtained
EnjuParser_T54 433-435 IN denotes in
EnjuParser_T55 436-441 CD denotes seven
EnjuParser_T56 442-447 NNS denotes steps
EnjuParser_T57 447-448 -COMMA- denotes ,
EnjuParser_T58 449-452 VBD denotes was
EnjuParser_T59 453-457 RB denotes also
EnjuParser_T60 458-467 VBN denotes developed
EnjuParser_T61 468-470 TO denotes to
EnjuParser_T62 471-476 VB denotes prove
EnjuParser_T63 477-480 DT denotes the
EnjuParser_T64 481-488 NN denotes utility
EnjuParser_T65 489-491 IN denotes of
EnjuParser_T66 492-493 DT denotes a
EnjuParser_T67 494-502 NN denotes hexanoyl
EnjuParser_T68 503-514 JJ denotes ester-based
EnjuParser_T69 515-525 JJ denotes orthogonal
EnjuParser_T70 526-536 NN denotes protection
EnjuParser_T71 537-545 NN denotes strategy
EnjuParser_T72 547-550 DT denotes The
EnjuParser_T73 551-559 NN denotes hexanoyl
EnjuParser_T74 560-570 NN denotes protection
EnjuParser_T75 571-579 NN denotes strategy
EnjuParser_T76 580-588 VBD denotes provided
EnjuParser_T77 589-592 PDT denotes all
EnjuParser_T78 593-596 DT denotes the
EnjuParser_T79 597-606 NN denotes flavonoid
EnjuParser_T80 607-620 NNS denotes intermediates
EnjuParser_T81 621-625 IN denotes with
EnjuParser_T82 626-630 JJ denotes good
EnjuParser_T83 631-641 NN denotes solubility
EnjuParser_T84 642-645 CC denotes and
EnjuParser_T85 646-656 NN denotes reactivity
EnjuParser_T86 656-657 -COMMA- denotes ,
EnjuParser_T87 658-665 VBD denotes enabled
EnjuParser_T88 666-675 JJ denotes efficient
EnjuParser_T89 676-685 JJ denotes selective
EnjuParser_T90 686-696 NN denotes protection
EnjuParser_T91 697-700 CC denotes and
EnjuParser_T92 701-714 NN denotes glycosylation
EnjuParser_T93 714-715 -COMMA- denotes ,
EnjuParser_T94 716-719 CC denotes and
EnjuParser_T95 720-728 VBD denotes provided
EnjuParser_T96 729-730 DT denotes a
EnjuParser_T97 731-740 JJ denotes practical
EnjuParser_T98 741-744 CC denotes and
EnjuParser_T99 745-754 JJ denotes effective
EnjuParser_T100 755-764 JJ denotes synthetic
EnjuParser_T101 765-773 NN denotes strategy
EnjuParser_T102 774-777 IN denotes for
EnjuParser_T103 778-788 NNS denotes flavonoids
EnjuParser_T104 788-789 -COMMA- denotes ,
EnjuParser_T105 790-798 VBG denotes starting
EnjuParser_T106 799-803 IN denotes from
EnjuParser_T107 804-816 RB denotes commercially
EnjuParser_T108 817-826 JJ denotes available
EnjuParser_T109 827-834 NN denotes flavone
EnjuParser_R0 EnjuParser_T3 EnjuParser_T0 arg1Of synthesis,The
EnjuParser_R1 EnjuParser_T3 EnjuParser_T1 arg1Of synthesis,first
EnjuParser_R2 EnjuParser_T3 EnjuParser_T2 arg1Of synthesis,total
EnjuParser_R3 EnjuParser_T3 EnjuParser_T4 arg1Of synthesis,of
EnjuParser_R4 EnjuParser_T6 EnjuParser_T4 arg2Of apigenin,of
EnjuParser_R5 EnjuParser_T6 EnjuParser_T5 arg1Of apigenin,7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl
EnjuParser_R6 EnjuParser_T3 EnjuParser_T7 arg1Of synthesis,via
EnjuParser_R7 EnjuParser_T12 EnjuParser_T7 arg2Of strategy,via
EnjuParser_R8 EnjuParser_T12 EnjuParser_T8 arg1Of strategy,a
EnjuParser_R9 EnjuParser_T12 EnjuParser_T9 arg1Of strategy,hexanoyl
EnjuParser_R10 EnjuParser_T12 EnjuParser_T10 arg1Of strategy,ester-based
EnjuParser_R11 EnjuParser_T12 EnjuParser_T11 arg1Of strategy,protection
EnjuParser_R12 EnjuParser_T16 EnjuParser_T13 arg1Of synthesis,The
EnjuParser_R13 EnjuParser_T16 EnjuParser_T14 arg1Of synthesis,first
EnjuParser_R14 EnjuParser_T16 EnjuParser_T15 arg1Of synthesis,total
EnjuParser_R15 EnjuParser_T16 EnjuParser_T17 arg1Of synthesis,of
EnjuParser_R16 EnjuParser_T19 EnjuParser_T17 arg2Of apigenin,of
EnjuParser_R17 EnjuParser_T19 EnjuParser_T18 arg1Of apigenin,7-O-beta-D-glucopyranosyl-4'-O-alpha-L-rhamnopyranosyl
EnjuParser_R18 EnjuParser_T19 EnjuParser_T20 arg1Of apigenin,1
EnjuParser_R19 EnjuParser_T16 EnjuParser_T21 arg1Of synthesis,","
EnjuParser_R20 EnjuParser_T16 EnjuParser_T22 arg1Of synthesis,which
EnjuParser_R21 EnjuParser_T16 EnjuParser_T23 arg1Of synthesis,exhibits
EnjuParser_R22 EnjuParser_T28 EnjuParser_T23 arg2Of and,exhibits
EnjuParser_R23 EnjuParser_T28 EnjuParser_T24 arg1Of and,good
EnjuParser_R24 EnjuParser_T27 EnjuParser_T25 arg1Of virus,anti-hepatitis
EnjuParser_R25 EnjuParser_T27 EnjuParser_T26 arg1Of virus,B
EnjuParser_R26 EnjuParser_T27 EnjuParser_T28 arg1Of virus,and
EnjuParser_R27 EnjuParser_T30 EnjuParser_T28 arg2Of activities,and
EnjuParser_R28 EnjuParser_T30 EnjuParser_T29 arg1Of activities,anti-stroke
EnjuParser_R29 EnjuParser_T33 EnjuParser_T31 arg1Of accomplished,","
EnjuParser_R30 EnjuParser_T16 EnjuParser_T32 arg1Of synthesis,was
EnjuParser_R31 EnjuParser_T33 EnjuParser_T32 arg2Of accomplished,was
EnjuParser_R32 EnjuParser_T16 EnjuParser_T33 arg2Of synthesis,accomplished
EnjuParser_R33 EnjuParser_T33 EnjuParser_T34 arg1Of accomplished,in
EnjuParser_R34 EnjuParser_T37 EnjuParser_T34 arg2Of and,in
EnjuParser_R35 EnjuParser_T36 EnjuParser_T35 arg1Of steps,six
EnjuParser_R36 EnjuParser_T36 EnjuParser_T37 arg1Of steps,and
EnjuParser_R37 EnjuParser_T39 EnjuParser_T37 arg2Of %,and
EnjuParser_R38 EnjuParser_T39 EnjuParser_T38 arg1Of %,20
EnjuParser_R39 EnjuParser_T41 EnjuParser_T40 arg1Of yield,overall
EnjuParser_R40 EnjuParser_T42 EnjuParser_T41 arg1Of from,yield
EnjuParser_R41 EnjuParser_T39 EnjuParser_T42 arg1Of %,from
EnjuParser_R42 EnjuParser_T43 EnjuParser_T42 arg2Of apigenin,from
EnjuParser_R43 EnjuParser_T46 EnjuParser_T44 arg1Of route,Another
EnjuParser_R44 EnjuParser_T46 EnjuParser_T45 arg1Of route,synthetic
EnjuParser_R45 EnjuParser_T46 EnjuParser_T47 arg1Of route,","
EnjuParser_R46 EnjuParser_T53 EnjuParser_T48 arg1Of obtained,in
EnjuParser_R47 EnjuParser_T46 EnjuParser_T48 arg2Of route,in
EnjuParser_R48 EnjuParser_T46 EnjuParser_T49 arg1Of route,which
EnjuParser_R49 EnjuParser_T51 EnjuParser_T50 arg1Of target,the
EnjuParser_R50 EnjuParser_T51 EnjuParser_T52 arg1Of target,was
EnjuParser_R51 EnjuParser_T53 EnjuParser_T52 arg2Of obtained,was
EnjuParser_R52 EnjuParser_T51 EnjuParser_T53 arg2Of target,obtained
EnjuParser_R53 EnjuParser_T53 EnjuParser_T54 arg1Of obtained,in
EnjuParser_R54 EnjuParser_T56 EnjuParser_T54 arg2Of steps,in
EnjuParser_R55 EnjuParser_T56 EnjuParser_T55 arg1Of steps,seven
EnjuParser_R56 EnjuParser_T60 EnjuParser_T57 arg1Of developed,","
EnjuParser_R57 EnjuParser_T46 EnjuParser_T58 arg1Of route,was
EnjuParser_R58 EnjuParser_T60 EnjuParser_T58 arg2Of developed,was
EnjuParser_R59 EnjuParser_T60 EnjuParser_T59 arg1Of developed,also
EnjuParser_R60 EnjuParser_T46 EnjuParser_T60 arg2Of route,developed
EnjuParser_R61 EnjuParser_T62 EnjuParser_T61 arg1Of prove,to
EnjuParser_R62 EnjuParser_T60 EnjuParser_T61 modOf developed,to
EnjuParser_R63 EnjuParser_T64 EnjuParser_T62 arg2Of utility,prove
EnjuParser_R64 EnjuParser_T64 EnjuParser_T63 arg1Of utility,the
EnjuParser_R65 EnjuParser_T64 EnjuParser_T65 arg1Of utility,of
EnjuParser_R66 EnjuParser_T71 EnjuParser_T65 arg2Of strategy,of
EnjuParser_R67 EnjuParser_T71 EnjuParser_T66 arg1Of strategy,a
EnjuParser_R68 EnjuParser_T71 EnjuParser_T67 arg1Of strategy,hexanoyl
EnjuParser_R69 EnjuParser_T71 EnjuParser_T68 arg1Of strategy,ester-based
EnjuParser_R70 EnjuParser_T71 EnjuParser_T69 arg1Of strategy,orthogonal
EnjuParser_R71 EnjuParser_T71 EnjuParser_T70 arg1Of strategy,protection
EnjuParser_R72 EnjuParser_T75 EnjuParser_T72 arg1Of strategy,The
EnjuParser_R73 EnjuParser_T75 EnjuParser_T73 arg1Of strategy,hexanoyl
EnjuParser_R74 EnjuParser_T75 EnjuParser_T74 arg1Of strategy,protection
EnjuParser_R75 EnjuParser_T75 EnjuParser_T76 arg1Of strategy,provided
EnjuParser_R76 EnjuParser_T80 EnjuParser_T76 arg2Of intermediates,provided
EnjuParser_R77 EnjuParser_T80 EnjuParser_T77 arg1Of intermediates,all
EnjuParser_R78 EnjuParser_T80 EnjuParser_T78 arg1Of intermediates,the
EnjuParser_R79 EnjuParser_T80 EnjuParser_T79 arg1Of intermediates,flavonoid
EnjuParser_R80 EnjuParser_T80 EnjuParser_T81 arg1Of intermediates,with
EnjuParser_R81 EnjuParser_T84 EnjuParser_T81 arg2Of and,with
EnjuParser_R82 EnjuParser_T84 EnjuParser_T82 arg1Of and,good
EnjuParser_R83 EnjuParser_T83 EnjuParser_T84 arg1Of solubility,and
EnjuParser_R84 EnjuParser_T85 EnjuParser_T84 arg2Of reactivity,and
EnjuParser_R85 EnjuParser_T76 EnjuParser_T86 arg1Of provided,","
EnjuParser_R86 EnjuParser_T87 EnjuParser_T86 arg2Of enabled,","
EnjuParser_R87 EnjuParser_T75 EnjuParser_T87 arg1Of strategy,enabled
EnjuParser_R88 EnjuParser_T91 EnjuParser_T87 arg2Of and,enabled
EnjuParser_R89 EnjuParser_T91 EnjuParser_T88 arg1Of and,efficient
EnjuParser_R90 EnjuParser_T91 EnjuParser_T89 arg1Of and,selective
EnjuParser_R91 EnjuParser_T90 EnjuParser_T91 arg1Of protection,and
EnjuParser_R92 EnjuParser_T92 EnjuParser_T91 arg2Of glycosylation,and
EnjuParser_R93 EnjuParser_T94 EnjuParser_T93 arg1Of and,","
EnjuParser_R94 EnjuParser_T86 EnjuParser_T94 arg1Of ",",and
EnjuParser_R95 EnjuParser_T95 EnjuParser_T94 arg2Of provided,and
EnjuParser_R96 EnjuParser_T75 EnjuParser_T95 arg1Of strategy,provided
EnjuParser_R97 EnjuParser_T101 EnjuParser_T95 arg2Of strategy,provided
EnjuParser_R98 EnjuParser_T101 EnjuParser_T96 arg1Of strategy,a
EnjuParser_R99 EnjuParser_T101 EnjuParser_T97 arg1Of strategy,practical
EnjuParser_R100 EnjuParser_T97 EnjuParser_T98 arg1Of practical,and
EnjuParser_R101 EnjuParser_T100 EnjuParser_T98 arg2Of synthetic,and
EnjuParser_R102 EnjuParser_T100 EnjuParser_T99 arg1Of synthetic,effective
EnjuParser_R103 EnjuParser_T101 EnjuParser_T100 arg1Of strategy,synthetic
EnjuParser_R104 EnjuParser_T101 EnjuParser_T102 arg1Of strategy,for
EnjuParser_R105 EnjuParser_T103 EnjuParser_T102 arg2Of flavonoids,for
EnjuParser_R106 EnjuParser_T94 EnjuParser_T104 arg1Of and,","
EnjuParser_R107 EnjuParser_T94 EnjuParser_T105 modOf and,starting
EnjuParser_R108 EnjuParser_T105 EnjuParser_T106 arg1Of starting,from
EnjuParser_R109 EnjuParser_T109 EnjuParser_T106 arg2Of flavone,from
EnjuParser_R110 EnjuParser_T108 EnjuParser_T107 arg1Of available,commercially
EnjuParser_R111 EnjuParser_T109 EnjuParser_T108 arg1Of flavone,available

mondo_disease

Id Subject Object Predicate Lexical cue mondo_id
T1 262-273 Disease denotes hepatitis B http://purl.obolibrary.org/obo/MONDO_0005344
T2 289-295 Disease denotes stroke http://purl.obolibrary.org/obo/MONDO_0005098|http://purl.obolibrary.org/obo/MONDO_0011057

GlyCosmos15-HP

Id Subject Object Predicate Lexical cue hp_id
T1 262-271 Phenotype denotes hepatitis HP:0012115
T2 289-295 Phenotype denotes stroke HP:0001297

NCBITAXON

Id Subject Object Predicate Lexical cue db_id
T1 262-279 OrganismTaxon denotes hepatitis B virus 10407