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PubMed:16125686 JSONTXT

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GlyCosmos6-Glycan-Motif-Image

Id Subject Object Predicate Lexical cue image
T1 80-87 Glycan_Motif denotes glucose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG
T2 107-116 Glycan_Motif denotes galactose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G68158BT|https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G65889KE
T4 270-277 Glycan_Motif denotes glucose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG
T5 279-282 Glycan_Motif denotes Glc https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG
T6 309-318 Glycan_Motif denotes galactose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G68158BT|https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G65889KE
T8 320-323 Glycan_Motif denotes Gal https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G68158BT
T9 637-640 Glycan_Motif denotes Glc https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG
T10 645-648 Glycan_Motif denotes Gal https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G68158BT
T11 983-990 Glycan_Motif denotes glucose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG
T12 1130-1139 Glycan_Motif denotes galactose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G68158BT|https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G65889KE
T14 1727-1734 Glycan_Motif denotes glucose https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG

GlyCosmos6-Glycan-Motif-Structure

Id Subject Object Predicate Lexical cue
T1 80-87 https://glytoucan.org/Structures/Glycans/G15021LG denotes glucose
T2 107-116 https://glytoucan.org/Structures/Glycans/G65889KE denotes galactose
T3 107-116 https://glytoucan.org/Structures/Glycans/G68158BT denotes galactose
T4 270-277 https://glytoucan.org/Structures/Glycans/G15021LG denotes glucose
T5 309-318 https://glytoucan.org/Structures/Glycans/G65889KE denotes galactose
T6 309-318 https://glytoucan.org/Structures/Glycans/G68158BT denotes galactose
T7 983-990 https://glytoucan.org/Structures/Glycans/G15021LG denotes glucose
T8 1130-1139 https://glytoucan.org/Structures/Glycans/G65889KE denotes galactose
T9 1130-1139 https://glytoucan.org/Structures/Glycans/G68158BT denotes galactose
T10 1727-1734 https://glytoucan.org/Structures/Glycans/G15021LG denotes glucose

Glycosmos6-MAT

Id Subject Object Predicate Lexical cue
T1 1330-1334 http://purl.obolibrary.org/obo/MAT_0000091 denotes hand

sentences

Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-147 Sentence denotes Investigations of different carbohydrate anomers in copper(II) complexes with D-glucose, D-fructose, and D-galactose by Raman and EPR spectroscopy.
TextSentencer_T2 148-384 Sentence denotes With the aim of verifying different carbohydrate anomers coordinated to copper(II) ions, some copper(II) complexes with D-glucose (Glc), D-fructose (Fru), and D-galactose (Gal) were prepared and investigated by spectroscopic techniques.
TextSentencer_T3 385-503 Sentence denotes Their compositions were verified by elemental, ICP-AES and thermal analyses, in addition to conductivity measurements.
TextSentencer_T4 504-728 Sentence denotes The compounds isolated were consistent with the formula Na2[Cu2(carbohydrate)3].8H2O and Na[Cu2(carbohydrate)3].6H2O for the aldoses Glc and Gal, respectively, and Na2[Cu3(carbohydrate)4].8H2O in the case of the ketose, Fru.
TextSentencer_T5 729-892 Sentence denotes EPR spectra of these solids showed a rhombic environment around the metal center and suggested the presence of different anomers of the carbohydrates in each case.
TextSentencer_T6 893-1085 Sentence denotes By Raman spectroscopy, it was possible to verify the predominance of the beta anomer of d-glucose in the corresponding copper complex, while in the free ligand the alpha anomer is predominant.
TextSentencer_T7 1086-1316 Sentence denotes In the case of the analogous complex with d-galactose, the spectrum of the complex shows bands of both anomers (alpha and beta) in approximately the same relative intensities as those observed in the isolated free ligand spectrum.
TextSentencer_T8 1317-1515 Sentence denotes On the other hand, for the complex with d-fructose a mixture of both furanose (five-membered ring) and pyranose (six-membered ring) structures was detected with prevalence of the furanose structure.
TextSentencer_T9 1516-1787 Sentence denotes Based on variations in the relative intensities of characteristic Raman bands, the binding site for copper in the fructose ligand was identified as most likely the 1-CH2OH and the anomeric 1-OH, while in beta-D-glucose it is presumably the anomeric 1-OH and the O-5 atom.
TextSentencer_T10 1788-1961 Sentence denotes These results indicated that EPR and Raman spectroscopy are suitable supporting techniques for the characterization of carbohydrate anomers coordinated to paramagnetic ions.
T1 0-147 Sentence denotes Investigations of different carbohydrate anomers in copper(II) complexes with D-glucose, D-fructose, and D-galactose by Raman and EPR spectroscopy.
T2 148-384 Sentence denotes With the aim of verifying different carbohydrate anomers coordinated to copper(II) ions, some copper(II) complexes with D-glucose (Glc), D-fructose (Fru), and D-galactose (Gal) were prepared and investigated by spectroscopic techniques.
T3 385-503 Sentence denotes Their compositions were verified by elemental, ICP-AES and thermal analyses, in addition to conductivity measurements.
T4 504-728 Sentence denotes The compounds isolated were consistent with the formula Na2[Cu2(carbohydrate)3].8H2O and Na[Cu2(carbohydrate)3].6H2O for the aldoses Glc and Gal, respectively, and Na2[Cu3(carbohydrate)4].8H2O in the case of the ketose, Fru.
T5 729-892 Sentence denotes EPR spectra of these solids showed a rhombic environment around the metal center and suggested the presence of different anomers of the carbohydrates in each case.
T6 893-1085 Sentence denotes By Raman spectroscopy, it was possible to verify the predominance of the beta anomer of d-glucose in the corresponding copper complex, while in the free ligand the alpha anomer is predominant.
T7 1086-1316 Sentence denotes In the case of the analogous complex with d-galactose, the spectrum of the complex shows bands of both anomers (alpha and beta) in approximately the same relative intensities as those observed in the isolated free ligand spectrum.
T8 1317-1515 Sentence denotes On the other hand, for the complex with d-fructose a mixture of both furanose (five-membered ring) and pyranose (six-membered ring) structures was detected with prevalence of the furanose structure.
T9 1516-1787 Sentence denotes Based on variations in the relative intensities of characteristic Raman bands, the binding site for copper in the fructose ligand was identified as most likely the 1-CH2OH and the anomeric 1-OH, while in beta-D-glucose it is presumably the anomeric 1-OH and the O-5 atom.
T10 1788-1961 Sentence denotes These results indicated that EPR and Raman spectroscopy are suitable supporting techniques for the characterization of carbohydrate anomers coordinated to paramagnetic ions.

mondo_disease

Id Subject Object Predicate Lexical cue mondo_id
T1 432-435 Disease denotes ICP http://purl.obolibrary.org/obo/MONDO_0019072

Anatomy-MAT

Id Subject Object Predicate Lexical cue mat_id
T1 1330-1334 Body_part denotes hand http://purl.obolibrary.org/obo/MAT_0000091

Anatomy-UBERON

Id Subject Object Predicate Lexical cue uberon_id
T1 1330-1334 Body_part denotes hand http://purl.obolibrary.org/obo/UBERON_0002398