| Id |
Subject |
Object |
Predicate |
Lexical cue |
| TextSentencer_T1 |
0-139 |
Sentence |
denotes |
New 6-butylamino-6-deoxycellulose and 6-deoxy-6-pyridiniumcellulose derivatives with highest regioselectivity and completeness of reaction. |
| TextSentencer_T2 |
140-272 |
Sentence |
denotes |
This paper investigates the nucleophilic substitution (S(N)) reactions of tosylcellulose with butylamine and pyridine, respectively. |
| TextSentencer_T3 |
273-684 |
Sentence |
denotes |
The S(N) reactions of tosylcellulose 1 (DS(Total) 2.02; DS(C-6) 1.0) with butylamine carried out at 25, 50, 75 and 100 degrees C in both dimethyl sulfoxide (DMSO) and pure butylamine showed that the regioselectivity of substitution at C-6 of cellulose is temperature dependent: the highest regioselectivity at C-6 can be reached at 25 and 50 degrees C; substitution at C-2 also occurred at 75 and 100 degrees C. |
| TextSentencer_T4 |
685-772 |
Sentence |
denotes |
The substitution speed in pure butylamine is greater than that in the presence of DMSO. |
| TextSentencer_T5 |
773-910 |
Sentence |
denotes |
A complete and regioselective substitution at C-6 with a DS of 1.0 was obtained under the conditions of 50 degrees C, 40 h in butylamine. |
| TextSentencer_T6 |
911-1031 |
Sentence |
denotes |
The substitution reactions of 1 with pyridine carried out at 25, 50, 75 and 100 degrees C for 24h in DMSO did not occur. |
| TextSentencer_T7 |
1032-1229 |
Sentence |
denotes |
In contrast to this the S(N) reactions done in pure pyridine showed that a temperature- and steric-dependent, regioselective substitution took place at C-6 at temperatures from 25 to 145 degrees C. |
| TextSentencer_T8 |
1230-1383 |
Sentence |
denotes |
The highest regioselectivity and completeness at C-6 can be obtained at 100 degrees C for 90 h, whereas at 145 degrees C substitution also occurs at C-2. |
| TextSentencer_T9 |
1384-1443 |
Sentence |
denotes |
The results were proved by 1H NMR and 13C NMR spectroscopy. |
| T1 |
0-139 |
Sentence |
denotes |
New 6-butylamino-6-deoxycellulose and 6-deoxy-6-pyridiniumcellulose derivatives with highest regioselectivity and completeness of reaction. |
| T2 |
140-272 |
Sentence |
denotes |
This paper investigates the nucleophilic substitution (S(N)) reactions of tosylcellulose with butylamine and pyridine, respectively. |
| T3 |
273-684 |
Sentence |
denotes |
The S(N) reactions of tosylcellulose 1 (DS(Total) 2.02; DS(C-6) 1.0) with butylamine carried out at 25, 50, 75 and 100 degrees C in both dimethyl sulfoxide (DMSO) and pure butylamine showed that the regioselectivity of substitution at C-6 of cellulose is temperature dependent: the highest regioselectivity at C-6 can be reached at 25 and 50 degrees C; substitution at C-2 also occurred at 75 and 100 degrees C. |
| T4 |
685-772 |
Sentence |
denotes |
The substitution speed in pure butylamine is greater than that in the presence of DMSO. |
| T5 |
773-910 |
Sentence |
denotes |
A complete and regioselective substitution at C-6 with a DS of 1.0 was obtained under the conditions of 50 degrees C, 40 h in butylamine. |
| T6 |
911-1031 |
Sentence |
denotes |
The substitution reactions of 1 with pyridine carried out at 25, 50, 75 and 100 degrees C for 24h in DMSO did not occur. |
| T7 |
1032-1229 |
Sentence |
denotes |
In contrast to this the S(N) reactions done in pure pyridine showed that a temperature- and steric-dependent, regioselective substitution took place at C-6 at temperatures from 25 to 145 degrees C. |
| T8 |
1230-1383 |
Sentence |
denotes |
The highest regioselectivity and completeness at C-6 can be obtained at 100 degrees C for 90 h, whereas at 145 degrees C substitution also occurs at C-2. |
| T9 |
1384-1443 |
Sentence |
denotes |
The results were proved by 1H NMR and 13C NMR spectroscopy. |
