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Id Subject Object Predicate Lexical cue
TextSentencer_T1 0-86 Sentence denotes 1,5-Anhydro-D-fructose; a versatile chiral building block: biochemistry and chemistry.
TextSentencer_T2 87-277 Sentence denotes There is a steadily increasing need to expand sustainable resources, and carbohydrates are anticipated to play an important role in this respect, both for bulk and fine chemical preparation.
TextSentencer_T3 278-358 Sentence denotes The enzyme alpha-(1-->4)-glucan lyase degrades starch to 1,5-anhydro-D-fructose.
TextSentencer_T4 359-601 Sentence denotes This compound, which has three different functional properties, a prochiral center together with a permanent pyran ring, renders it a potential chiral building block for the synthesis of valuable and potentially biologically active compounds.
TextSentencer_T5 602-705 Sentence denotes 1,5-Anhydro-D-fructose is found in natural materials as a degradation product of alpha-(1-->4)-glucans.
TextSentencer_T6 706-828 Sentence denotes The occurrence of lyases and the metabolism of 1,5-anhydro-D-fructose are reviewed in the biological part of this article.
TextSentencer_T7 829-1036 Sentence denotes In the chemical part, the elucidated structure of 1,5-anhydro-D-fructose will be presented together with simple stereoselective conversions into hydroxy/amino 1,5-anhydro hexitols and a nojirimycin analogue.
TextSentencer_T8 1037-1195 Sentence denotes Synthesis of 6-O-acylated derivatives of 1,5-anhydro-D-fructose substituted with long fatty acid residues is carried out using commercially available enzymes.
TextSentencer_T9 1196-1268 Sentence denotes Those reactions lead to compounds with potential emulsifying properties.
TextSentencer_T10 1269-1387 Sentence denotes The use of protected derivatives of 1,5-anhydro-D-fructose for the synthesis of natural products is likewise reviewed.
TextSentencer_T11 1388-1474 Sentence denotes The potential utilization of this chemical building block is far from being exhausted.
TextSentencer_T12 1475-1806 Sentence denotes Since 1,5-anhydro-D-fructose now is accessible in larger amounts through a simple-enzyme catalyzed degradation of starch by alpha-(1-->4)-glucan lyase, the application of 1,5-anhydro-D-fructose may be considered a valuable contribution to the utilization of carbohydrates as the most abundant resource of sustainable raw materials.
T1 0-86 Sentence denotes 1,5-Anhydro-D-fructose; a versatile chiral building block: biochemistry and chemistry.
T2 87-277 Sentence denotes There is a steadily increasing need to expand sustainable resources, and carbohydrates are anticipated to play an important role in this respect, both for bulk and fine chemical preparation.
T3 278-358 Sentence denotes The enzyme alpha-(1-->4)-glucan lyase degrades starch to 1,5-anhydro-D-fructose.
T4 359-601 Sentence denotes This compound, which has three different functional properties, a prochiral center together with a permanent pyran ring, renders it a potential chiral building block for the synthesis of valuable and potentially biologically active compounds.
T5 602-705 Sentence denotes 1,5-Anhydro-D-fructose is found in natural materials as a degradation product of alpha-(1-->4)-glucans.
T6 706-828 Sentence denotes The occurrence of lyases and the metabolism of 1,5-anhydro-D-fructose are reviewed in the biological part of this article.
T7 829-1036 Sentence denotes In the chemical part, the elucidated structure of 1,5-anhydro-D-fructose will be presented together with simple stereoselective conversions into hydroxy/amino 1,5-anhydro hexitols and a nojirimycin analogue.
T8 1037-1195 Sentence denotes Synthesis of 6-O-acylated derivatives of 1,5-anhydro-D-fructose substituted with long fatty acid residues is carried out using commercially available enzymes.
T9 1196-1268 Sentence denotes Those reactions lead to compounds with potential emulsifying properties.
T10 1269-1387 Sentence denotes The use of protected derivatives of 1,5-anhydro-D-fructose for the synthesis of natural products is likewise reviewed.
T11 1388-1474 Sentence denotes The potential utilization of this chemical building block is far from being exhausted.
T12 1475-1806 Sentence denotes Since 1,5-anhydro-D-fructose now is accessible in larger amounts through a simple-enzyme catalyzed degradation of starch by alpha-(1-->4)-glucan lyase, the application of 1,5-anhydro-D-fructose may be considered a valuable contribution to the utilization of carbohydrates as the most abundant resource of sustainable raw materials.