PubMed:11996839
Annnotations
sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
TextSentencer_T1 | 0-133 | Sentence | denotes | The crystal structure of the alpha-cellobiose.2 NaI.2 H(2)O complex in the context of related structures and conformational analysis. |
TextSentencer_T2 | 134-324 | Sentence | denotes | The crystal structure of beta-D-glucopyranosyl-(1-->4)-alpha-D-glucopyranose (alpha-cellobiose) in a complex with water and NaI was determined with Mo K(alpha) radiation at 150 K to R=0.027. |
TextSentencer_T3 | 325-433 | Sentence | denotes | The space group is P2(1) and unit cell dimensions are a=9.0188, b=12.2536, c=10.9016 A, beta=97.162 degrees. |
TextSentencer_T4 | 434-620 | Sentence | denotes | There are no direct hydrogen bonds among cellobiose molecules, and the usual intramolecular hydrogen bond between O-3 and O-5' is replaced by a bridge involving Na+, O-3, O-5', and O-6'. |
TextSentencer_T5 | 621-656 | Sentence | denotes | Both Na+ have sixfold coordination. |
TextSentencer_T6 | 657-736 | Sentence | denotes | One I(-) accepts six donor hydroxyl groups and three C-H***I(-) hydrogen bonds. |
TextSentencer_T7 | 737-816 | Sentence | denotes | The other accepts three hydroxyls, one Na+, and five C-H***I(-) hydrogen bonds. |
TextSentencer_T8 | 817-988 | Sentence | denotes | Linkage torsion angles phi(O-5) and psi(C-5) are -73.6 and -105.3 degrees, respectively (phi(H)=47.1 degrees and psi(H)=14.6 degrees ), probably induced by the Na+ bridge. |
TextSentencer_T9 | 989-1076 | Sentence | denotes | This conformation is in a separate cluster in phi,psi space from most similar linkages. |
TextSentencer_T10 | 1077-1193 | Sentence | denotes | Both C-6-O-H and C-6'-O-H are gg, while the C-6'-O-H groups from molecules not in the cluster have gt conformations. |
TextSentencer_T11 | 1194-1319 | Sentence | denotes | Hybrid molecular mechanics/quantum mechanics calculations show <1.2 kcal/mol strain for any of the small-molecule structures. |
TextSentencer_T12 | 1320-1442 | Sentence | denotes | Extrapolation of the NaI cellobiose geometry to a cellulose molecule gives a left-handed helix with 2.9 residues per turn. |
TextSentencer_T13 | 1443-1578 | Sentence | denotes | The energy map and small-molecule crystal structures imply that cellulose helices having 2.5 and 3.0 residues per turn are left-handed. |
T1 | 0-133 | Sentence | denotes | The crystal structure of the alpha-cellobiose.2 NaI.2 H(2)O complex in the context of related structures and conformational analysis. |
T2 | 134-324 | Sentence | denotes | The crystal structure of beta-D-glucopyranosyl-(1-->4)-alpha-D-glucopyranose (alpha-cellobiose) in a complex with water and NaI was determined with Mo K(alpha) radiation at 150 K to R=0.027. |
T3 | 325-433 | Sentence | denotes | The space group is P2(1) and unit cell dimensions are a=9.0188, b=12.2536, c=10.9016 A, beta=97.162 degrees. |
T4 | 434-620 | Sentence | denotes | There are no direct hydrogen bonds among cellobiose molecules, and the usual intramolecular hydrogen bond between O-3 and O-5' is replaced by a bridge involving Na+, O-3, O-5', and O-6'. |
T5 | 621-656 | Sentence | denotes | Both Na+ have sixfold coordination. |
T6 | 657-736 | Sentence | denotes | One I(-) accepts six donor hydroxyl groups and three C-H***I(-) hydrogen bonds. |
T7 | 737-816 | Sentence | denotes | The other accepts three hydroxyls, one Na+, and five C-H***I(-) hydrogen bonds. |
T8 | 817-988 | Sentence | denotes | Linkage torsion angles phi(O-5) and psi(C-5) are -73.6 and -105.3 degrees, respectively (phi(H)=47.1 degrees and psi(H)=14.6 degrees ), probably induced by the Na+ bridge. |
T9 | 989-1076 | Sentence | denotes | This conformation is in a separate cluster in phi,psi space from most similar linkages. |
T10 | 1077-1193 | Sentence | denotes | Both C-6-O-H and C-6'-O-H are gg, while the C-6'-O-H groups from molecules not in the cluster have gt conformations. |
T11 | 1194-1319 | Sentence | denotes | Hybrid molecular mechanics/quantum mechanics calculations show <1.2 kcal/mol strain for any of the small-molecule structures. |
T12 | 1320-1442 | Sentence | denotes | Extrapolation of the NaI cellobiose geometry to a cellulose molecule gives a left-handed helix with 2.9 residues per turn. |
T13 | 1443-1578 | Sentence | denotes | The energy map and small-molecule crystal structures imply that cellulose helices having 2.5 and 3.0 residues per turn are left-handed. |
Glycosmos6-MAT
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T1 | 1402-1408 | http://purl.obolibrary.org/obo/MAT_0000091 | denotes | handed |
T2 | 1571-1577 | http://purl.obolibrary.org/obo/MAT_0000091 | denotes | handed |
Glycan-GlyCosmos
Id | Subject | Object | Predicate | Lexical cue | image |
---|---|---|---|---|---|
T1 | 35-45 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T2 | 218-228 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T3 | 475-485 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T4 | 1345-1355 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
GlyCosmos15-UBERON
Id | Subject | Object | Predicate | Lexical cue | uberon_id |
---|---|---|---|---|---|
T1 | 329-334 | Body_part | denotes | space | http://purl.obolibrary.org/obo/UBERON_0000464 |
T2 | 1043-1048 | Body_part | denotes | space | http://purl.obolibrary.org/obo/UBERON_0000464 |
T3 | 1409-1414 | Body_part | denotes | helix | http://purl.obolibrary.org/obo/UBERON_0002488 |
GlyCosmos15-MAT
Id | Subject | Object | Predicate | Lexical cue | mat_id |
---|---|---|---|---|---|
T1 | 1402-1408 | Body_part | denotes | handed | http://purl.obolibrary.org/obo/MAT_0000091 |
T2 | 1571-1577 | Body_part | denotes | handed | http://purl.obolibrary.org/obo/MAT_0000091 |
sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
TextSentencer_T1 | 0-133 | Sentence | denotes | The crystal structure of the alpha-cellobiose.2 NaI.2 H(2)O complex in the context of related structures and conformational analysis. |
TextSentencer_T2 | 134-324 | Sentence | denotes | The crystal structure of beta-D-glucopyranosyl-(1-->4)-alpha-D-glucopyranose (alpha-cellobiose) in a complex with water and NaI was determined with Mo K(alpha) radiation at 150 K to R=0.027. |
TextSentencer_T3 | 325-433 | Sentence | denotes | The space group is P2(1) and unit cell dimensions are a=9.0188, b=12.2536, c=10.9016 A, beta=97.162 degrees. |
TextSentencer_T4 | 434-620 | Sentence | denotes | There are no direct hydrogen bonds among cellobiose molecules, and the usual intramolecular hydrogen bond between O-3 and O-5' is replaced by a bridge involving Na+, O-3, O-5', and O-6'. |
TextSentencer_T5 | 621-656 | Sentence | denotes | Both Na+ have sixfold coordination. |
TextSentencer_T6 | 657-736 | Sentence | denotes | One I(-) accepts six donor hydroxyl groups and three C-H***I(-) hydrogen bonds. |
TextSentencer_T7 | 737-816 | Sentence | denotes | The other accepts three hydroxyls, one Na+, and five C-H***I(-) hydrogen bonds. |
TextSentencer_T8 | 817-988 | Sentence | denotes | Linkage torsion angles phi(O-5) and psi(C-5) are -73.6 and -105.3 degrees, respectively (phi(H)=47.1 degrees and psi(H)=14.6 degrees ), probably induced by the Na+ bridge. |
TextSentencer_T9 | 989-1076 | Sentence | denotes | This conformation is in a separate cluster in phi,psi space from most similar linkages. |
TextSentencer_T10 | 1077-1193 | Sentence | denotes | Both C-6-O-H and C-6'-O-H are gg, while the C-6'-O-H groups from molecules not in the cluster have gt conformations. |
TextSentencer_T11 | 1194-1319 | Sentence | denotes | Hybrid molecular mechanics/quantum mechanics calculations show <1.2 kcal/mol strain for any of the small-molecule structures. |
TextSentencer_T12 | 1320-1442 | Sentence | denotes | Extrapolation of the NaI cellobiose geometry to a cellulose molecule gives a left-handed helix with 2.9 residues per turn. |
TextSentencer_T13 | 1443-1578 | Sentence | denotes | The energy map and small-molecule crystal structures imply that cellulose helices having 2.5 and 3.0 residues per turn are left-handed. |
T1 | 0-133 | Sentence | denotes | The crystal structure of the alpha-cellobiose.2 NaI.2 H(2)O complex in the context of related structures and conformational analysis. |
T2 | 134-324 | Sentence | denotes | The crystal structure of beta-D-glucopyranosyl-(1-->4)-alpha-D-glucopyranose (alpha-cellobiose) in a complex with water and NaI was determined with Mo K(alpha) radiation at 150 K to R=0.027. |
T3 | 325-433 | Sentence | denotes | The space group is P2(1) and unit cell dimensions are a=9.0188, b=12.2536, c=10.9016 A, beta=97.162 degrees. |
T4 | 434-620 | Sentence | denotes | There are no direct hydrogen bonds among cellobiose molecules, and the usual intramolecular hydrogen bond between O-3 and O-5' is replaced by a bridge involving Na+, O-3, O-5', and O-6'. |
T5 | 621-656 | Sentence | denotes | Both Na+ have sixfold coordination. |
T6 | 657-736 | Sentence | denotes | One I(-) accepts six donor hydroxyl groups and three C-H***I(-) hydrogen bonds. |
T7 | 737-816 | Sentence | denotes | The other accepts three hydroxyls, one Na+, and five C-H***I(-) hydrogen bonds. |
T8 | 817-988 | Sentence | denotes | Linkage torsion angles phi(O-5) and psi(C-5) are -73.6 and -105.3 degrees, respectively (phi(H)=47.1 degrees and psi(H)=14.6 degrees ), probably induced by the Na+ bridge. |
T9 | 989-1076 | Sentence | denotes | This conformation is in a separate cluster in phi,psi space from most similar linkages. |
T10 | 1077-1193 | Sentence | denotes | Both C-6-O-H and C-6'-O-H are gg, while the C-6'-O-H groups from molecules not in the cluster have gt conformations. |
T11 | 1194-1319 | Sentence | denotes | Hybrid molecular mechanics/quantum mechanics calculations show <1.2 kcal/mol strain for any of the small-molecule structures. |
T12 | 1320-1442 | Sentence | denotes | Extrapolation of the NaI cellobiose geometry to a cellulose molecule gives a left-handed helix with 2.9 residues per turn. |
T13 | 1443-1578 | Sentence | denotes | The energy map and small-molecule crystal structures imply that cellulose helices having 2.5 and 3.0 residues per turn are left-handed. |
GlyCosmos15-Sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T1 | 0-133 | Sentence | denotes | The crystal structure of the alpha-cellobiose.2 NaI.2 H(2)O complex in the context of related structures and conformational analysis. |
T2 | 134-324 | Sentence | denotes | The crystal structure of beta-D-glucopyranosyl-(1-->4)-alpha-D-glucopyranose (alpha-cellobiose) in a complex with water and NaI was determined with Mo K(alpha) radiation at 150 K to R=0.027. |
T3 | 325-433 | Sentence | denotes | The space group is P2(1) and unit cell dimensions are a=9.0188, b=12.2536, c=10.9016 A, beta=97.162 degrees. |
T4 | 434-620 | Sentence | denotes | There are no direct hydrogen bonds among cellobiose molecules, and the usual intramolecular hydrogen bond between O-3 and O-5' is replaced by a bridge involving Na+, O-3, O-5', and O-6'. |
T5 | 621-656 | Sentence | denotes | Both Na+ have sixfold coordination. |
T6 | 657-736 | Sentence | denotes | One I(-) accepts six donor hydroxyl groups and three C-H***I(-) hydrogen bonds. |
T7 | 737-816 | Sentence | denotes | The other accepts three hydroxyls, one Na+, and five C-H***I(-) hydrogen bonds. |
T8 | 817-988 | Sentence | denotes | Linkage torsion angles phi(O-5) and psi(C-5) are -73.6 and -105.3 degrees, respectively (phi(H)=47.1 degrees and psi(H)=14.6 degrees ), probably induced by the Na+ bridge. |
T9 | 989-1076 | Sentence | denotes | This conformation is in a separate cluster in phi,psi space from most similar linkages. |
T10 | 1077-1193 | Sentence | denotes | Both C-6-O-H and C-6'-O-H are gg, while the C-6'-O-H groups from molecules not in the cluster have gt conformations. |
T11 | 1194-1319 | Sentence | denotes | Hybrid molecular mechanics/quantum mechanics calculations show <1.2 kcal/mol strain for any of the small-molecule structures. |
T12 | 1320-1442 | Sentence | denotes | Extrapolation of the NaI cellobiose geometry to a cellulose molecule gives a left-handed helix with 2.9 residues per turn. |
T13 | 1443-1578 | Sentence | denotes | The energy map and small-molecule crystal structures imply that cellulose helices having 2.5 and 3.0 residues per turn are left-handed. |
GlyCosmos15-Glycan
Id | Subject | Object | Predicate | Lexical cue | image |
---|---|---|---|---|---|
T1 | 35-45 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T2 | 218-228 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T3 | 475-485 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
T4 | 1345-1355 | Glycan | denotes | cellobiose | https://api.glycosmos.org/wurcs2image/latest/png/binary/G55560AP |
Anatomy-UBERON
Id | Subject | Object | Predicate | Lexical cue | uberon_id |
---|---|---|---|---|---|
T1 | 329-334 | Body_part | denotes | space | http://purl.obolibrary.org/obo/UBERON_0000464 |
T2 | 1043-1048 | Body_part | denotes | space | http://purl.obolibrary.org/obo/UBERON_0000464 |
T3 | 1409-1414 | Body_part | denotes | helix | http://purl.obolibrary.org/obo/UBERON_0002488 |
Anatomy-MAT
Id | Subject | Object | Predicate | Lexical cue | mat_id |
---|---|---|---|---|---|
T1 | 1402-1408 | Body_part | denotes | handed | http://purl.obolibrary.org/obo/MAT_0000091 |
T2 | 1571-1577 | Body_part | denotes | handed | http://purl.obolibrary.org/obo/MAT_0000091 |