PubMed:10839118 JSONTXT

{"project":"GlyCosmos600-Glycan-Motif-Structure","denotations":[{"id":"T1","span":{"begin":140,"end":147},"obj":"https://glytoucan.org/Structures/Glycans/G70323CJ"},{"id":"T2","span":{"begin":170,"end":177},"obj":"https://glytoucan.org/Structures/Glycans/G15021LG"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"NCBITAXON","denotations":[{"id":"PD-NCBITaxon-B_T1","span":{"begin":83,"end":91},"obj":"http://purl.bioontology.org/ontology/NCBITAXON/620"},{"id":"PD-NCBITaxon-B_T2","span":{"begin":1156,"end":1164},"obj":"http://purl.bioontology.org/ontology/NCBITAXON/620"},{"id":"PD-NCBITaxon-B_T3","span":{"begin":83,"end":103},"obj":"http://purl.bioontology.org/ontology/NCBITAXON/622"},{"id":"PD-NCBITaxon-B_T4","span":{"begin":1156,"end":1176},"obj":"http://purl.bioontology.org/ontology/NCBITAXON/622"},{"id":"T1","span":{"begin":83,"end":103},"obj":"OrganismTaxon"},{"id":"T2","span":{"begin":1156,"end":1176},"obj":"OrganismTaxon"}],"attributes":[{"id":"A1","pred":"db_id","subj":"T1","obj":"NCBItxid:622"},{"id":"A2","pred":"db_id","subj":"T2","obj":"NCBItxid:622"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"GlyCosmos6-Glycan-Motif-Image","denotations":[{"id":"T1","span":{"begin":140,"end":147},"obj":"Glycan_Motif"},{"id":"T2","span":{"begin":170,"end":177},"obj":"Glycan_Motif"}],"attributes":[{"id":"A1","pred":"image","subj":"T1","obj":"https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G70323CJ"},{"id":"A2","pred":"image","subj":"T2","obj":"https://api.glycosmos.org/wurcs2image/0.10.0/png/binary/G15021LG"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"sentences","denotations":[{"id":"TextSentencer_T1","span":{"begin":0,"end":111},"obj":"Sentence"},{"id":"TextSentencer_T2","span":{"begin":112,"end":675},"obj":"Sentence"},{"id":"TextSentencer_T3","span":{"begin":676,"end":1184},"obj":"Sentence"},{"id":"T1","span":{"begin":0,"end":111},"obj":"Sentence"},{"id":"T2","span":{"begin":112,"end":675},"obj":"Sentence"},{"id":"T3","span":{"begin":676,"end":1184},"obj":"Sentence"}],"namespaces":[{"prefix":"_base","uri":"http://pubannotation.org/ontology/tao.owl#"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"GlyCosmos6-Glycan-Motif-Structure","denotations":[{"id":"T1","span":{"begin":140,"end":147},"obj":"https://glytoucan.org/Structures/Glycans/G70323CJ"},{"id":"T2","span":{"begin":170,"end":177},"obj":"https://glytoucan.org/Structures/Glycans/G15021LG"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"GlyCosmos6-CLO","denotations":[{"id":"T1","span":{"begin":475,"end":478},"obj":"http://purl.obolibrary.org/obo/CLO_0007169"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"GlyCosmos600-FMA","denotations":[{"id":"PD-FMA-PAE-B_T1","span":{"begin":128,"end":136},"obj":"http://purl.org/sig/ont/fma/fma82803"},{"id":"PD-FMA-PAE-B_T2","span":{"begin":140,"end":147},"obj":"http://purl.org/sig/ont/fma/fma82801"},{"id":"PD-FMA-PAE-B_T3","span":{"begin":170,"end":177},"obj":"http://purl.org/sig/ont/fma/fma82743"},{"id":"PD-FMA-PAE-B_T4","span":{"begin":197,"end":209},"obj":"http://purl.org/sig/ont/fma/fma82744"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"GlyCosmos600-CLO","denotations":[{"id":"T1","span":{"begin":475,"end":478},"obj":"http://purl.obolibrary.org/obo/CLO_0007169"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"glycosmos-test-glycan-structure","denotations":[{"id":"PD-GlycanStructures-B_T1","span":{"begin":170,"end":177},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa210/trivialname"},{"id":"PD-GlycanStructures-B_T2","span":{"begin":140,"end":147},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa218/trivialname"},{"id":"PD-GlycanStructures-B_T3","span":{"begin":128,"end":136},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa224/trivialname"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

{"project":"glycosmos-test-structure-v1","denotations":[{"id":"PD-GlycanStructures-B_T3","span":{"begin":128,"end":136},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa224/trivialname"},{"id":"PD-GlycanStructures-B_T2","span":{"begin":140,"end":147},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa218/trivialname"},{"id":"PD-GlycanStructures-B_T1","span":{"begin":170,"end":177},"obj":"http://rdf.glyconavi.org/CarTNa/CarTNa210/trivialname"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}

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ser_T153","obj":"EnjuParser_T154"},{"id":"EnjuParser_R157","pred":"arg2Of","subj":"EnjuParser_T157","obj":"EnjuParser_T154"},{"id":"EnjuParser_R158","pred":"arg1Of","subj":"EnjuParser_T157","obj":"EnjuParser_T155"},{"id":"EnjuParser_R159","pred":"arg1Of","subj":"EnjuParser_T157","obj":"EnjuParser_T156"},{"id":"EnjuParser_R160","pred":"arg1Of","subj":"EnjuParser_T157","obj":"EnjuParser_T158"},{"id":"EnjuParser_R161","pred":"arg2Of","subj":"EnjuParser_T160","obj":"EnjuParser_T158"},{"id":"EnjuParser_R162","pred":"arg1Of","subj":"EnjuParser_T160","obj":"EnjuParser_T159"},{"id":"EnjuParser_R163","pred":"arg1Of","subj":"EnjuParser_T160","obj":"EnjuParser_T161"},{"id":"EnjuParser_R164","pred":"arg2Of","subj":"EnjuParser_T164","obj":"EnjuParser_T161"},{"id":"EnjuParser_R165","pred":"arg1Of","subj":"EnjuParser_T164","obj":"EnjuParser_T162"},{"id":"EnjuParser_R166","pred":"arg1Of","subj":"EnjuParser_T164","obj":"EnjuParser_T163"},{"id":"EnjuParser_R167","pred":"arg1Of","subj":"EnjuParser_T164","obj":"EnjuParser_T165"}],"namespaces":[{"prefix":"_base","uri":"http://kmcs.nii.ac.jp/enju/"}],"text":"Synthesis of the tetrasaccharide related to the repeating unit of the antigen from Shigella dysenteriae type 5.\nStarting from L-rhamnose, D-mannose and 2-amino-2-deoxy-D-glucose hydrochloride, two disaccharide blocks, namely, ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamnopyranos yl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-alpha-D-mannopyranoside and 2-(trimethylsilyl)ethyl 2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-4,6-di-O-benzy l-2-deoxy-2-phthalimido-beta-D-glucopyranoside, were synthesised and then allowed to react in the presence of N-iodosuccinimide and trifluoromethane sulfonic acid to give a tetrasaccharide derivative. This compound was converted into 2-(trimethylsilyl)ethyl 2,4-di-O-benzyl-3-O-[(R)-1-(methoxycarbonyl)ethyl]-alpha-L-rhamno- pyranosyl-(1--\u003e3)-2-O-acetyl-4,6-di-O-benzyl-alpha-D-mannopyranosyl-(1-- \u003e4)-2-O-acetyl-3,6-di-O-benzyl-alpha-D-mannopyranosyl-(1--\u003e3)-2-acetamid o-4,6-di-O-benzyl-2-deoxy-beta-D-glucopyranoside, which on hydrogenolysis, afforded the methyl ester 2-(trimethylsilyl)ethyl glycoside of the tetrasaccharide related to the repeating unit of the O-antigen from Shigella dysenteriae type 5."}