> top > docs > PMC:7571312 > spans > 75406-76299 > annotations

PMC:7571312 / 75406-76299 JSONTXT

Annnotations TAB JSON ListView MergeView

LitCovid-PD-CLO

Id Subject Object Predicate Lexical cue
T569 406-407 http://purl.obolibrary.org/obo/CLO_0001020 denotes a
T570 451-453 http://purl.obolibrary.org/obo/CL_0000453 denotes LC
T571 550-551 http://purl.obolibrary.org/obo/CLO_0001020 denotes a
T572 850-852 http://purl.obolibrary.org/obo/CLO_0007874 denotes MS
T573 885-890 http://purl.obolibrary.org/obo/CLO_0007706 denotes M + H

LitCovid-PD-CHEBI

Id Subject Object Predicate Lexical cue chebi_id
T972 25-28 Chemical denotes oxo http://purl.obolibrary.org/obo/CHEBI_46629
T973 59-65 Chemical denotes methyl http://purl.obolibrary.org/obo/CHEBI_32875|http://purl.obolibrary.org/obo/CHEBI_29309
T975 66-72 Chemical denotes propyl http://purl.obolibrary.org/obo/CHEBI_26308
T976 74-76 Chemical denotes N2 http://purl.obolibrary.org/obo/CHEBI_17997
T977 78-97 Chemical denotes tert-butoxycarbonyl http://purl.obolibrary.org/obo/CHEBI_48502
T978 101-107 Chemical denotes methyl http://purl.obolibrary.org/obo/CHEBI_32875|http://purl.obolibrary.org/obo/CHEBI_29309
T980 184-194 Chemical denotes tert-butyl http://purl.obolibrary.org/obo/CHEBI_30355
T981 189-194 Chemical denotes butyl http://purl.obolibrary.org/obo/CHEBI_41264
T982 226-229 Chemical denotes oxo http://purl.obolibrary.org/obo/CHEBI_46629
T983 260-266 Chemical denotes methyl http://purl.obolibrary.org/obo/CHEBI_32875|http://purl.obolibrary.org/obo/CHEBI_29309
T985 267-273 Chemical denotes propyl http://purl.obolibrary.org/obo/CHEBI_26308
T986 274-279 Chemical denotes amino http://purl.obolibrary.org/obo/CHEBI_46882
T987 302-312 Chemical denotes 2-oxoethyl http://purl.obolibrary.org/obo/CHEBI_46886
T988 313-322 Chemical denotes carbamate http://purl.obolibrary.org/obo/CHEBI_13941
T989 340-343 Chemical denotes Boc http://purl.obolibrary.org/obo/CHEBI_48502
T990 347-354 Chemical denotes t-butyl http://purl.obolibrary.org/obo/CHEBI_30355
T991 349-354 Chemical denotes butyl http://purl.obolibrary.org/obo/CHEBI_41264
T992 356-359 Chemical denotes Ala http://purl.obolibrary.org/obo/CHEBI_16977|http://purl.obolibrary.org/obo/CHEBI_46217
T994 451-453 Chemical denotes LC http://purl.obolibrary.org/obo/CHEBI_73582
T995 468-472 Chemical denotes SiO2 http://purl.obolibrary.org/obo/CHEBI_30563
T996 481-489 Chemical denotes methanol http://purl.obolibrary.org/obo/CHEBI_17790
T997 490-500 Chemical denotes chloroform http://purl.obolibrary.org/obo/CHEBI_35255
T998 571-573 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T999 579-583 Chemical denotes DMSO http://purl.obolibrary.org/obo/CHEBI_28262
T1000 609-611 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1001 623-625 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1002 661-663 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1003 719-721 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1004 733-735 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1005 761-763 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1006 775-777 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1007 789-791 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T1008 850-852 Chemical denotes MS http://purl.obolibrary.org/obo/CHEBI_73613

LitCovid-sentences

Id Subject Object Predicate Lexical cue
T460 0-126 Sentence denotes N1-((1S)-3-(Benzyloxy)-2-oxo-1-{[(3S)-2-oxopyrrolidin-3-yl]methyl}propyl)-N2-(tert-butoxycarbonyl)-4-methyl-l-leucinamide (33)
T461 127-420 Sentence denotes Following the procedure described for the preparation of tert-butyl [(1S)-2-[((1S)-3-(benzyloxy)-2-oxo-1-{[(3S)-2-oxopyrrolidin-3-yl]methyl}propyl)amino]-1-(cyclohexylmethyl)-2-oxoethyl]carbamate but substituting Boc-(β t-butyl)-Ala-OH and making noncritical variations provided a brown syrup.
T462 421-570 Sentence denotes This material was purified by LC (33 g 230–400 SiO2, 1–2.5% methanol/chloroform) to afford 258 mg (55%) of the title compound as a light yellow foam.
T463 571-893 Sentence denotes 1H NMR (DMSO-d6) δ 8.23 (d, J = 8 Hz, 1H), 7.62 (s, 1H), 7.32 (m, 5H), 6.96 (d, J = 8 Hz, 1H), 4.46 (s, 2H), 4.35–4.33 (m, 2H), 4.21 (d, J = 16 Hz, 1H), 3.95 (m, 1H), 3.09 (m, 2H), 2.24 (m, 1H), 2.07 (m, 1H), 1.92 (m, 1H), 1.58 (m, 2H), 1.46 (m, 2H), 1.35 (s, 9H), 0.87 (m, 9H); MS (ESI+) for C27H41N3O6m/z 504.2 (M + H)+.

LitCovid-PubTator

Id Subject Object Predicate Lexical cue tao:has_database_id
1608 340-343 Gene denotes Boc Gene:91653
1609 468-472 Chemical denotes SiO2
1610 481-489 Chemical denotes methanol MESH:D000432
1611 490-500 Chemical denotes chloroform MESH:D002725