PMC:7571312 / 115766-116672
Annnotations
LitCovid-PD-CLO
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T72 | 284-285 | http://purl.obolibrary.org/obo/CLO_0001020 | denotes | a |
T73 | 859-861 | http://purl.obolibrary.org/obo/CLO_0007874 | denotes | MS |
T74 | 898-903 | http://purl.obolibrary.org/obo/CLO_0007706 | denotes | M – H |
LitCovid-PD-CHEBI
Id | Subject | Object | Predicate | Lexical cue | chebi_id |
---|---|---|---|---|---|
T54398 | 77-83 | Chemical | denotes | chloro | http://purl.obolibrary.org/obo/CHEBI_47853 |
T34240 | 86-89 | Chemical | denotes | oxo | http://purl.obolibrary.org/obo/CHEBI_46629 |
T22447 | 120-126 | Chemical | denotes | methyl | http://purl.obolibrary.org/obo/CHEBI_32875|http://purl.obolibrary.org/obo/CHEBI_29309 |
T32734 | 127-133 | Chemical | denotes | propyl | http://purl.obolibrary.org/obo/CHEBI_26308 |
T16199 | 134-139 | Chemical | denotes | amino | http://purl.obolibrary.org/obo/CHEBI_46882 |
T54946 | 140-148 | Chemical | denotes | carbonyl | http://purl.obolibrary.org/obo/CHEBI_23019 |
T29365 | 150-163 | Chemical | denotes | 3-methylbutyl | http://purl.obolibrary.org/obo/CHEBI_30359 |
T13674 | 167-174 | Chemical | denotes | methoxy | http://purl.obolibrary.org/obo/CHEBI_32772|http://purl.obolibrary.org/obo/CHEBI_44520 |
T74571 | 175-184 | Chemical | denotes | 1H-indole | http://purl.obolibrary.org/obo/CHEBI_16881 |
T80619 | 175-177 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T24048 | 178-184 | Chemical | denotes | indole | http://purl.obolibrary.org/obo/CHEBI_35581 |
T3894 | 187-198 | Chemical | denotes | carboxamide | http://purl.obolibrary.org/obo/CHEBI_23004|http://purl.obolibrary.org/obo/CHEBI_37622 |
T27297 | 216-222 | Chemical | denotes | indole | http://purl.obolibrary.org/obo/CHEBI_16881|http://purl.obolibrary.org/obo/CHEBI_35581 |
T2161 | 225-240 | Chemical | denotes | carboxylic acid | http://purl.obolibrary.org/obo/CHEBI_33575 |
T56450 | 236-240 | Chemical | denotes | acid | http://purl.obolibrary.org/obo/CHEBI_37527 |
T39246 | 378-386 | Chemical | denotes | methanol | http://purl.obolibrary.org/obo/CHEBI_17790 |
T33818 | 387-402 | Chemical | denotes | dichloromethane | http://purl.obolibrary.org/obo/CHEBI_15767 |
T20847 | 468-470 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T74007 | 485-489 | Chemical | denotes | DMSO | http://purl.obolibrary.org/obo/CHEBI_28262 |
T16982 | 506-508 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T63708 | 532-534 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T2955 | 558-560 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T44220 | 603-605 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T9758 | 629-631 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T33550 | 643-645 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T69327 | 669-671 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T40756 | 745-747 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T90580 | 764-766 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T82858 | 783-785 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T32498 | 859-861 | Chemical | denotes | MS | http://purl.obolibrary.org/obo/CHEBI_73613 |
LitCovid-sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T624 | 0-304 | Sentence | denotes | Following the procedure described for the preparation of N-((1S)-1-{[((1S)-3-chloro-2-oxo-1-{[(3S)-2-oxopyrrolidin-3-yl]methyl}propyl)amino]carbonyl}-3-methylbutyl)-4-methoxy-1H-indole-2-carboxamide but substituting indole-2-carboxylic acid and making noncritical variations provided a crude orange foam. |
T625 | 305-467 | Sentence | denotes | This material was purified by Biotage flash chromatography, eluting with methanol/dichloromethane to afford the title compound as an off-white solid, 1.75 g, 82%. |
T626 | 468-906 | Sentence | denotes | 1H NMR (400 MHz, DMSO-d6) δ 11.58 (s, 1H), 8.64 (d, J = 7.8 Hz, 1H), 8.50 (d, J = 7.8 Hz, 1H), 7.55–7.69 (m, 2H), 7.42 (d, J = 8.3 Hz, 1H), 7.26 (d, J = 1.5 Hz, 1H), 7.16 (m, 1H), 7.02 (t, J = 7.5 Hz, 1H), 4.53–4.66 (m, 2H), 4.39–4.52 (m, 2H), 2.94–3.18 (m, 2H), 2.22–2.35 (m, 1H), 2.03–2.16 (m, 1H), 1.89–2.02 (m, 1H), 1.45–1.82 (m, 5H), 0.93 (d, J = 6.3 Hz, 3H), 0.88 (d, J = 6.3 Hz, 3H); MS (APCI−) for C23H29N4O4Cl m/z 459.1 (M – H)−. |
LitCovid-PubTator
Id | Subject | Object | Predicate | Lexical cue | tao:has_database_id |
---|---|---|---|---|---|
2049 | 216-240 | Chemical | denotes | indole-2-carboxylic acid | MESH:C058980 |
2050 | 378-386 | Chemical | denotes | methanol | MESH:D000432 |
2051 | 387-402 | Chemical | denotes | dichloromethane | MESH:D008752 |