PMC:7291971 / 11929-12304
Annnotations
LitCovid-PMC-OGER-BB
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T243 | 22-35 | CHEBI:23447;CHEBI:23447 | denotes | dinucleosides |
T244 | 47-70 | CHEBI:75508;CHEBI:75508 | denotes | 4-chlorobenzenesulfonyl |
T245 | 71-79 | CHEBI:17996;CHEBI:17996 | denotes | chloride |
T246 | 119-121 | CHEBI:86228;CHEBI:86228 | denotes | 4- |
T247 | 121-127 | CHEBI:47853;CHEBI:47853 | denotes | chloro |
T248 | 127-147 | CHEBI:86228;CHEBI:86228 | denotes | -3-nitrobenzaldehyde |
T249 | 149-153 | CHEBI:16236;CHEBI:16236 | denotes | AcOH |
T250 | 218-238 | CHEBI:28105;CHEBI:28105 | denotes | 4-chlorobenzaldehyde |
T251 | 240-244 | CHEBI:28619;CHEBI:28619 | denotes | AcOH |
T252 | 309-312 | CHEBI:15377;CHEBI:15377 | denotes | H2O |
LitCovid-PubTator
Id | Subject | Object | Predicate | Lexical cue | tao:has_database_id |
---|---|---|---|---|---|
146 | 22-35 | Chemical | denotes | dinucleosides | |
147 | 47-79 | Chemical | denotes | 4-chlorobenzenesulfonyl chloride | |
148 | 81-85 | Chemical | denotes | NEt3 | |
149 | 87-93 | Chemical | denotes | CH2Cl2 | |
150 | 119-147 | Chemical | denotes | 4-chloro-3-nitrobenzaldehyde | |
151 | 149-153 | Chemical | denotes | AcOH | |
152 | 155-158 | Chemical | denotes | DCE | |
153 | 180-190 | Chemical | denotes | NaBH(OAc)3 | |
154 | 218-238 | Chemical | denotes | 4-chlorobenzaldehyde | MESH:C052044 |
155 | 240-244 | Chemical | denotes | AcOH | |
156 | 246-249 | Chemical | denotes | DCE | |
157 | 271-281 | Chemical | denotes | NaBH(OAc)3 | |
158 | 305-308 | Chemical | denotes | TFA | MESH:D014269 |
159 | 309-312 | Chemical | denotes | H2O |
LitCovid-PD-CLO
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T108 | 44-45 | http://purl.obolibrary.org/obo/CLO_0001020 | denotes | a |
T109 | 112-113 | http://purl.obolibrary.org/obo/CLO_0001021 | denotes | b |
T110 | 196-201 | http://purl.obolibrary.org/obo/CLO_0002096 | denotes | C, 16 |
T111 | 287-292 | http://purl.obolibrary.org/obo/CLO_0002096 | denotes | C, 16 |
T112 | 315-320 | http://purl.obolibrary.org/obo/CLO_0001196 | denotes | 2, 25 |
T113 | 330-332 | http://purl.obolibrary.org/obo/CLO_0001382 | denotes | 48 |
LitCovid-PD-CHEBI
Id | Subject | Object | Predicate | Lexical cue | chebi_id |
---|---|---|---|---|---|
T196 | 71-79 | Chemical | denotes | chloride | http://purl.obolibrary.org/obo/CHEBI_17996 |
T197 | 81-85 | Chemical | denotes | NEt3 | http://purl.obolibrary.org/obo/CHEBI_35026 |
T198 | 121-127 | Chemical | denotes | chloro | http://purl.obolibrary.org/obo/CHEBI_47853 |
T199 | 149-153 | Chemical | denotes | AcOH | http://purl.obolibrary.org/obo/CHEBI_15366 |
T200 | 155-158 | Chemical | denotes | DCE | http://purl.obolibrary.org/obo/CHEBI_27789 |
T201 | 218-238 | Chemical | denotes | 4-chlorobenzaldehyde | http://purl.obolibrary.org/obo/CHEBI_28105 |
T202 | 240-244 | Chemical | denotes | AcOH | http://purl.obolibrary.org/obo/CHEBI_15366 |
T203 | 246-249 | Chemical | denotes | DCE | http://purl.obolibrary.org/obo/CHEBI_27789 |
T204 | 305-308 | Chemical | denotes | TFA | http://purl.obolibrary.org/obo/CHEBI_45892 |
T205 | 309-312 | Chemical | denotes | H2O | http://purl.obolibrary.org/obo/CHEBI_15377 |
LitCovid-PD-GO-BP
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T28 | 9-18 | http://purl.obolibrary.org/obo/GO_0009058 | denotes | Synthesis |
LitCovid-sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T74 | 0-375 | Sentence | denotes | Scheme 4 Synthesis of dinucleosides 14–16. (a) 4-chlorobenzenesulfonyl chloride, NEt3, CH2Cl2, 0 °C, 3 h, 90%. (b) (i) 4-chloro-3-nitrobenzaldehyde, AcOH, DCE, 40 °C, 20 min; (ii) NaBH(OAc)3, 40 °C, 16 h, 87%. (c) (i) 4-chlorobenzaldehyde, AcOH, DCE, 40 °C, 20 min. (ii) NaBH(OAc)3, 40 °C, 16 h, 72%. (d) TFA/H2O 8/2, 25 °C, 3 h, 48% for 14; 6 h, 25% for 15; 6 h, 37% for 16. |