> top > docs > PMC:7571312 > spans > 54682-55728 > annotations

PMC:7571312 / 54682-55728 JSONTXT

Annnotations TAB JSON ListView MergeView

LitCovid-PD-CLO

Id Subject Object Predicate Lexical cue
T484 250-251 http://purl.obolibrary.org/obo/CLO_0001020 denotes a
T485 894-896 http://purl.obolibrary.org/obo/CLO_0007874 denotes MS
T486 929-934 http://purl.obolibrary.org/obo/CLO_0007706 denotes M + H

LitCovid-PD-CHEBI

Id Subject Object Predicate Lexical cue chebi_id
T44136 72-79 Chemical denotes methoxy http://purl.obolibrary.org/obo/CHEBI_32772|http://purl.obolibrary.org/obo/CHEBI_44520
T72315 80-93 Chemical denotes 1H-indol-2-yl http://purl.obolibrary.org/obo/CHEBI_51611
T80123 80-82 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T38371 94-102 Chemical denotes carbonyl http://purl.obolibrary.org/obo/CHEBI_23019
T84329 106-112 Chemical denotes leucyl http://purl.obolibrary.org/obo/CHEBI_32630|http://purl.obolibrary.org/obo/CHEBI_37904
T18805 113-118 Chemical denotes amino http://purl.obolibrary.org/obo/CHEBI_46882
T29990 122-125 Chemical denotes oxo http://purl.obolibrary.org/obo/CHEBI_46629
T16489 155-168 Chemical denotes butyl acetate http://purl.obolibrary.org/obo/CHEBI_31328
T52074 155-160 Chemical denotes butyl http://purl.obolibrary.org/obo/CHEBI_41264
T82193 161-168 Chemical denotes acetate http://purl.obolibrary.org/obo/CHEBI_30089|http://purl.obolibrary.org/obo/CHEBI_47622
T58673 186-206 Chemical denotes 4-methylbenzoic acid http://purl.obolibrary.org/obo/CHEBI_36635
T4356 188-206 Chemical denotes methylbenzoic acid http://purl.obolibrary.org/obo/CHEBI_25280
T58977 202-206 Chemical denotes acid http://purl.obolibrary.org/obo/CHEBI_37527
T76679 326-334 Chemical denotes methanol http://purl.obolibrary.org/obo/CHEBI_17790
T88844 335-350 Chemical denotes dichloromethane http://purl.obolibrary.org/obo/CHEBI_15767
T43261 397-399 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T87223 414-418 Chemical denotes DMSO http://purl.obolibrary.org/obo/CHEBI_28262
T97389 447-449 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T63097 473-475 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T52721 499-501 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T20525 539-541 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T70463 565-567 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T48645 617-619 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T85643 636-638 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T81008 662-664 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T19507 676-678 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T59206 695-697 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T17149 780-782 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T6479 799-801 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T95796 818-820 Chemical denotes 1H http://purl.obolibrary.org/obo/CHEBI_49637
T96393 894-896 Chemical denotes MS http://purl.obolibrary.org/obo/CHEBI_73613
T60033 970-973 Chemical denotes H2O http://purl.obolibrary.org/obo/CHEBI_15377
T82823 979-982 Chemical denotes DCM http://purl.obolibrary.org/obo/CHEBI_15767

LitCovid-sentences

Id Subject Object Predicate Lexical cue
T354 0-266 Sentence denotes Following the procedure described for the preparation of (3S)-3-({N-[(4-methoxy-1H-indol-2-yl)carbonyl]-l-leucyl}amino)-2-oxo-4-[(3S)-2-oxopyrrolidin-3-yl]butyl acetate but substituting 4-methylbenzoic acid and making noncritical variations provided a crude product.
T355 267-396 Sentence denotes This material was purified by Biotage MPLC (25 M, 2.5–4.5% methanol/dichloromethane) to afford 92 mg (44%) of the title compound.
T356 397-937 Sentence denotes 1H NMR (400 MHz, DMSO-d6) δ 11.59 (d, J = 1.8 Hz, 1H), 8.63 (d, J = 8.1 Hz, 1H), 8.46 (d, J = 7.6 Hz, 1H), 7.87 (d, J = 8.1 Hz, 2H), 7.65 (s, 1H), 7.37 (d, J = 1.8 Hz, 1H), 7.34 (d, J = 8.3 Hz, 2H), 7.08 (t, J = 8.0 Hz, 1H), 6.97–7.01 (m, 1H), 6.50 (d, J = 7.8 Hz, 1H), 5.09 (s, 1H), 5.03–5.20 (m, 1H), 4.43–4.52 (m, 2H), 3.87 (s, 3H), 3.04–3.17 (m, 2H), 2.38 (s, 3H), 2.28–2.34 (m, 1H), 2.06–2.14 (m, 1H), 1.96–2.06 (m, 1H), 1.51–1.78 (m, 5H), 0.94 (d, J = 6.3 Hz, 3H), 0.89 (d, J = 6.3 Hz, 3H); MS (ESI+) for C32H38N4O7m/z 591.2 (M + H)+.
T357 938-1011 Sentence denotes Anal. calcd for C32H38N4O7·0.10 H2O·0.11 DCM: C, 64.08; H, 6.43; N, 9.31.
T358 1012-1046 Sentence denotes Found: C, 64.36; H, 6.41; N, 8.92.

LitCovid-PD-HP

Id Subject Object Predicate Lexical cue hp_id
T8 979-982 Phenotype denotes DCM http://purl.obolibrary.org/obo/HP_0001644

LitCovid-PubTator

Id Subject Object Predicate Lexical cue tao:has_database_id
1238 186-206 Chemical denotes 4-methylbenzoic acid MESH:C009504
1239 326-334 Chemical denotes methanol MESH:D000432
1240 335-350 Chemical denotes dichloromethane MESH:D008752
1241 954-964 Chemical denotes C32H38N4O7
1242 970-973 Chemical denotes H2O
1243 979-982 Chemical denotes DCM MESH:D008752
1244 984-985 Chemical denotes C MESH:D002244
1245 1003-1004 Chemical denotes N MESH:D009584
1246 1019-1020 Chemical denotes C MESH:D002244
1247 1038-1039 Chemical denotes N MESH:D009584