PMC:7571312 / 101940-102681
Annnotations
LitCovid-PD-CLO
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T15 | 236-237 | http://purl.obolibrary.org/obo/CLO_0001020 | denotes | a |
T16 | 385-386 | http://purl.obolibrary.org/obo/CLO_0001020 | denotes | a |
T17 | 400-403 | http://purl.obolibrary.org/obo/CLO_0001310 | denotes | 351 |
T18 | 408-410 | http://purl.obolibrary.org/obo/CLO_0001313 | denotes | 36 |
T19 | 692-694 | http://purl.obolibrary.org/obo/CLO_0007874 | denotes | MS |
T20 | 700-702 | http://purl.obolibrary.org/obo/CLO_0053755 | denotes | ES |
T21 | 733-738 | http://purl.obolibrary.org/obo/CLO_0007706 | denotes | M – H |
LitCovid-PD-CHEBI
Id | Subject | Object | Predicate | Lexical cue | chebi_id |
---|---|---|---|---|---|
T33680 | 57-59 | Chemical | denotes | N2 | http://purl.obolibrary.org/obo/CHEBI_17997 |
T87508 | 61-80 | Chemical | denotes | tert-butoxycarbonyl | http://purl.obolibrary.org/obo/CHEBI_48502 |
T90688 | 93-99 | Chemical | denotes | chloro | http://purl.obolibrary.org/obo/CHEBI_47853 |
T85873 | 102-105 | Chemical | denotes | oxo | http://purl.obolibrary.org/obo/CHEBI_46629 |
T13091 | 136-142 | Chemical | denotes | methyl | http://purl.obolibrary.org/obo/CHEBI_32875|http://purl.obolibrary.org/obo/CHEBI_29309 |
T86710 | 143-149 | Chemical | denotes | propyl | http://purl.obolibrary.org/obo/CHEBI_26308 |
T29648 | 182-185 | Chemical | denotes | Boc | http://purl.obolibrary.org/obo/CHEBI_48502 |
T47981 | 186-189 | Chemical | denotes | Phe | http://purl.obolibrary.org/obo/CHEBI_17295|http://purl.obolibrary.org/obo/CHEBI_29997 |
T89287 | 328-336 | Chemical | denotes | methanol | http://purl.obolibrary.org/obo/CHEBI_17790 |
T5237 | 337-352 | Chemical | denotes | dichloromethane | http://purl.obolibrary.org/obo/CHEBI_15767 |
T93823 | 413-415 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T90226 | 430-435 | Chemical | denotes | CDCl3 | http://purl.obolibrary.org/obo/CHEBI_85365 |
T95940 | 448-450 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T91093 | 481-483 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T18151 | 507-509 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T17831 | 526-528 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T81758 | 540-542 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T32769 | 616-618 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T56438 | 635-637 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T24078 | 654-656 | Chemical | denotes | 1H | http://purl.obolibrary.org/obo/CHEBI_49637 |
T90628 | 692-694 | Chemical | denotes | MS | http://purl.obolibrary.org/obo/CHEBI_73613 |
T19605 | 700-702 | Chemical | denotes | ES | http://purl.obolibrary.org/obo/CHEBI_73509 |
LitCovid-sentences
Id | Subject | Object | Predicate | Lexical cue |
---|---|---|---|---|
T570 | 0-254 | Sentence | denotes | Following the procedure described for the preparation of N2-(tert-butoxycarbonyl)-N1-((1S)-3-chloro-2-oxo-1-{[(3S)-2-oxopyrrolidin-3-yl]methyl}propyl)-l-leucinamide but substituting Boc-Phe-OH and making noncritical variations provided a crude brown oil. |
T571 | 255-412 | Sentence | denotes | This material was purified by Biotage flash chromatography, eluting with methanol/dichloromethane to afford the title compound as a white solid, 351 mg, 36%. |
T572 | 413-741 | Sentence | denotes | 1H NMR (400 MHz, CDCl3) δ 8.02 (s, 1H), 7.19–7.31 (m, 5H), 5.77 (s, 1H), 5.10 (d, J = 6.1 Hz, 1H), 4.52–4.57 (m, 1H), 4.44 (m, 1H), 4.01–4.12 (m, 2H), 3.26–3.37 (m, 2H), 3.01–3.08 (m, 2H), 2.29–2.37 (m, 1H), 2.15–2.25 (m, 1H), 1.98–2.06 (m, 1H), 1.75–1.91 (m, 2H), 1.40 (s, 9H); MS (API-ES−) for C22H30N3O5Cl m/z 450.2 (M – H)−. |
LitCovid-PubTator
Id | Subject | Object | Predicate | Lexical cue | tao:has_database_id |
---|---|---|---|---|---|
1891 | 182-185 | Gene | denotes | Boc | Gene:91653 |
1892 | 328-336 | Chemical | denotes | methanol | MESH:D000432 |
1893 | 337-352 | Chemical | denotes | dichloromethane | MESH:D008752 |