We would like to acknowledge K. Montooth, P. Hudson, and five anonymous reviewers for providing helpful comments on drafts of the manuscript. We are indebted to J. Freytag, S. Dattagupta, D. Bergquist, R. Carney, and R. Sassen for the many discussions and advice provided. EEC acknowledges funding from the Center for Environmental Chemistry and Geochemistry at Pennsylvania State University and the Nancy Foster Scholarship Program at the National Oceanographic and Atmospheric Administration (NOAA). This work was supported by the U.S. Minerals Management Service, the NOAA National Undersea Research Program, and the National Science Foundation. Competing interests. The authors have declared that no competing interests exist.